中性 U(II) 芳基金属夹心配合物的合成与表征。
Synthesis and Characterization of a Neutral U(II) Arene Sandwich Complex.
机构信息
Department of Chemistry . Michigan State University , 578 S. Shaw Lane , East Lansing , Michigan 48824 , United States.
Department of Chemistry , Colorado State University , Fort Collins , Colorado 80523 , United States.
出版信息
J Am Chem Soc. 2018 Dec 19;140(50):17369-17373. doi: 10.1021/jacs.8b10888. Epub 2018 Dec 5.
Reduction of IU(NHAr) (Ar = 2,6-(2,4,6-PrCH)CH) results in a rare example of a U(II) complex, U(NHAr), and the first example that is a neutral species. Here, we show spectroscopic and magnetic studies that suggest a 5f6d valence electronic configuration for uranium, along with characterization of related U(III) complexes.
还原 IU(NHAr)（Ar = 2,6-(2,4,6-PrCH)CH）得到了一个罕见的 U(II) 配合物 U(NHAr)，也是首例中性物种。在这里，我们展示了光谱和磁性研究结果，表明铀具有 5f6d 价电子构型，并对相关的 U(III) 配合物进行了表征。
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