Osman Ahmed Galal, Raman Vijayasankar, Haider Saqlain, Ali Zulfiqar, Chittiboyina Amar G, Khan Ikhlas A
The University of Mississippi, School of Pharmacy, National Center for Natural Products Research, 1558 University Circle, University, MS 38677.
J AOAC Int. 2019 Mar 1;102(2):376-385. doi: 10.5740/jaoacint.18-0389. Epub 2019 Jan 15.
Spices and aromatic herbs have long been used by people to impart sensory appetizing elements, including aroma, flavor, and color, to foods and beverages in an effort to enhance their palatability. Herbs and spices exhibit a plethora of medicinal properties including antimicrobial and antioxidant properties. Spices serve as natural preservatives to delay food spoilage and extend shelf life. As spice trading has exponentially increased globally, herbs and spices have become prone to adulteration, which can be deliberate or unintentional. Deliberate adulteration is usually economically motivated, aimed at maximizing profit margins, whereas unintentional adulteration is often attributed to improper harvesting or processing of the plant material or collecting/substituting closely related species. Adulteration of herbs or spices with toxic ingredients such as Sudan dyes or metal salts (e.g., lead chromate) may result in serious public health consequences. To provide a concise account of ongoing adulteration issues with spices and herbs in order to enhance general awareness of the short- and longer-term implications of such fraud. Last twenty-years of literature on various aspects of spice adulteration including text books and online resources were gathered and compiled. In addition, a number of original reports have been published prior to year 2000 that are directly associated with adulteration of commonly traded herbs and spices were also included. The current review covers the role of spices and herbs in human life, adulteration of the commonly consumed spices and herbs, identification of their adulterants, as well as the most popular analytical techniques and methods used in their detection, including spectroscopic, chromatographic, electronic sensing, and deoxyribonucleic acid-based methodologies. Spices and herbs, being high-priced commodities, have been often subjected to adulteration in many ways which reduces their quality and potentially has harmful health implications. Adulteration is attributed primarily to increased demand or supply shortage of the spices and aromatic herbs. The motivation for spice fraud is largely attributed to economical interest to gain greater profit margins and such adulteration of spices can have serious implications for public health. To combat the adulteration of spices and herbs effectively, a range of analytical techniques across many different technologies have been developed. These techniques are expected to aid in the detection of adulterants and establish quantifiable concentrations for the compounds in question in various matrices, including spices and aromatic herbs.
长期以来,人们一直使用香料和芳香草本植物为食品和饮料增添感官上诱人的元素,包括香气、风味和颜色,以提高它们的适口性。草本植物和香料具有众多药用特性,包括抗菌和抗氧化特性。香料可作为天然防腐剂,延缓食物变质并延长保质期。随着全球香料贸易呈指数级增长,草本植物和香料容易出现掺假现象,这种掺假可能是故意的,也可能是无意的。故意掺假通常是出于经济动机,旨在最大化利润率,而无意掺假往往归因于植物材料收获或加工不当,或者采集/替代了密切相关的物种。用苏丹染料或金属盐(如铬酸铅)等有毒成分掺假草本植物或香料可能会导致严重的公共卫生后果。为了简要说明香料和草本植物目前存在的掺假问题,以提高人们对这种欺诈行为短期和长期影响的普遍认识。收集并汇编了过去二十年中关于香料掺假各个方面的文献,包括教科书和在线资源。此外,还纳入了一些2000年之前发表的与常见贸易草本植物和香料掺假直接相关的原始报告。本综述涵盖了香料和草本植物在人类生活中的作用、常见食用香料和草本植物的掺假情况、掺假物的鉴定,以及用于检测它们的最流行的分析技术和方法,包括光谱法、色谱法、电子传感法和基于脱氧核糖核酸的方法。香料和草本植物作为高价商品,常常以多种方式被掺假,这降低了它们的质量,并可能对健康产生有害影响。掺假主要归因于香料和芳香草本植物需求增加或供应短缺。香料欺诈的动机很大程度上归因于获取更高利润率的经济利益,而这种香料掺假可能会对公众健康产生严重影响。为了有效打击香料和草本植物的掺假行为,已经开发了一系列涵盖许多不同技术的分析技术。这些技术有望有助于检测掺假物,并确定各种基质(包括香料和芳香草本植物)中相关化合物的可量化浓度。