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KHCO和KHPO对乙烯爆炸的抑制作用。

Inhibition Effect of KHCO and KHPO on Ethylene Explosion.

作者信息

Wang Yang, Yang JingJing, He Jia, Wen XiaoPing, Ji WenTao, Wang Yan

机构信息

State Key Laboratory Cultivation Bases for Gas Geology and Gas Control, College of Safety Science and Engineering, Henan Polytechnic University, Jiaozuo 454003, China.

The Collaboration Innovation Center of Coal Safety Production of Henan Province, Henan Polytechnic University, Jiaozuo 454003, China.

出版信息

ACS Omega. 2023 Feb 14;8(8):7566-7574. doi: 10.1021/acsomega.2c06894. eCollection 2023 Feb 28.

Abstract

The explosion risk of ethylene (CH) seriously hinders safe development of its production and processing. To reduce the harm caused by CH explosion, an experimental study was conducted to assess the explosion inhibition characteristics of KHCO and KHPO powders. The experiments were conducted based on the explosion overpressure and flame propagation of the 6.5% CH-air mixture in a 5 L semi-closed explosion duct. Both the physical and chemical inhibition characteristics of the inhibitors were mechanistically assessed. The results showed that the 6.5% CH explosion pressure ( ) decreases by increasing the concentration of KHCO or KHPO powder. The inhibition effect of KHCO powder on the CH system explosion pressure was better than that of the KHPO powder under similar concentration conditions. Both powders significantly affected the flame propagation of the CH explosion. Compared with KHPO powder, KHCO powder had a better inhibition effect on the flame propagation speed, but its ability to reduce the flame luminance was less than KHPO powder. Finally, the inhibition mechanism(s) of KHCO and KHPO powders were revealed based on the powders' thermal characteristics and gas-phase reaction.

摘要

乙烯(CH)的爆炸风险严重阻碍了其生产和加工的安全发展。为减少CH爆炸造成的危害,开展了一项实验研究,以评估KHCO和KHPO粉末的抑爆特性。实验基于6.5%CH-空气混合物在5L半封闭爆炸管道中的爆炸超压和火焰传播进行。对抑制剂的物理和化学抑爆特性进行了机理评估。结果表明,通过增加KHCO或KHPO粉末的浓度,6.5%CH的爆炸压力( )会降低。在相似浓度条件下,KHCO粉末对CH体系爆炸压力的抑制效果优于KHPO粉末。两种粉末均对CH爆炸的火焰传播有显著影响。与KHPO粉末相比,KHCO粉末对火焰传播速度的抑制效果更好,但其降低火焰亮度的能力不如KHPO粉末。最后,基于粉末的热特性和气相反应揭示了KHCO和KHPO粉末的抑爆机理。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2bd7/9979324/cc93c49871de/ao2c06894_0004.jpg

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