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直流磁控溅射制备 TiAlV 薄膜在超高分子量聚乙烯上的结构、化学和力学研究。

Structural, chemical and mechanical study of TiAlV film on UHMWPE produced by DC magnetron sputtering.

机构信息

Universidad de Guadalajara-CUCEI, Guadalajara,Jalisco, México.

Universidad Politécnica del Valle de México, Tultitlán, Edo. México, México.

出版信息

J Mech Behav Biomed Mater. 2019 May;93:23-30. doi: 10.1016/j.jmbbm.2019.01.010. Epub 2019 Jan 12.

Abstract

Ultra High Molecular Weight Polyethylene (UHMWPE), with a semi-trapezoidal topography, and glass samples were coated with a TiAlV film using magnetron sputtering in order to study its structure, chemical composition and the adhesion film properties on the polymer surfaces. The magnetron sputtering is a PVD technique that depending on the deposited parameter produces a coating with structural, chemical and specific topographic characteristics that increase the electrical, mechanical, optical and biological surface properties of the organic compounds. The quantities of Vanadium (V) and Aluminum (Al) were similar to that of Ti64 alloy. The metallic film obtained presents α-Ti phase structure with a (200) preferential orientation. The TiAlV film on polymeric surfaces with semi-trapezoidal topography exhibit irregularities and uncoated zones but on the glass, the metallic coating was smooth and continuous. The scratch tests were carried out using an incremental load configuration with a Tribotechnic scratch tester equipment. The metallic film decreased the viscoelastic recovering of the polymeric surface but increased the load capacity. The metallic film did not present complete delamination but fractures and small zones of coating detachment were observed on all the scratch tracks.

摘要

超高分子量聚乙烯(UHMWPE),具有半梯形形貌,以及玻璃样品,均采用磁控溅射在其表面镀上 TiAlV 薄膜,以研究其结构、化学成分和薄膜在聚合物表面的附着性能。磁控溅射是一种 PVD 技术,根据沉积参数的不同,可以在涂层上产生具有结构、化学和特定形貌特征的涂层,从而提高有机化合物的电学、力学、光学和生物学表面性能。钒(V)和铝(Al)的含量与 Ti64 合金相似。所获得的金属膜呈现出具有(200)择优取向的α-Ti 相结构。在具有半梯形形貌的聚合物表面上的 TiAlV 薄膜表现出不规则和未涂层的区域,但在玻璃上,金属涂层是光滑和连续的。划痕试验使用 Tribotechnic 划痕测试仪设备的增量载荷配置进行。金属薄膜降低了聚合物表面的粘弹性恢复,但增加了承载能力。金属薄膜没有完全分层,但在所有划痕轨迹上都观察到了断裂和小的涂层脱落区域。

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