International Center for Young Scientists (ICYS) and International Center for Materials Nanoarchitectonics (MANA) National Institute for Materials Science (NIMS), 1-1 Namiki, Tsukuba, Ibaraki 305-0044, Japan.
Key Laboratory of Eco-Chemical Engineering, College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology (QUST), Qingdao 266042, China.
J Nanosci Nanotechnol. 2019 Jul 1;19(7):3673-3685. doi: 10.1166/jnn.2019.16745.
Hard- and soft-templating approaches are one of potential strategies for the fabrication of functional nanoporous carbon materials with desired morphologies and properties. Enormous efforts have been paid for understanding the synthetic mechanisms that strongly influence the materials design and applications. All of these investigations are crucial to encourage the application of hard- and soft-templating approaches for the precise synthesis of nanoporous carbon materials. In this review, we mainly summarize significant works employing different synthetic methods for making carbon materials with various pore sizes and functionalities. The content of the review article contains: (i) Hard-templating synthesis of microporous carbon from zeolites; (ii) Hard-templating synthesis of mesoporous carbon from mesoporous silica; (iii) Hard-templating synthesis of macroporous carbon; and (iv) Soft-templating synthesis of mesoporous carbon. This review aims to provide a detailed glimpse of hard- and soft-templating approaches for future development of functional nanoporous carbon materials.
硬模板和软模板方法是制备具有所需形貌和性能的功能性纳米多孔碳材料的一种有潜力的策略。人们付出了巨大的努力来理解强烈影响材料设计和应用的合成机制。所有这些研究对于鼓励硬模板和软模板方法在纳米多孔碳材料的精确合成中的应用都是至关重要的。在这篇综述中,我们主要总结了使用不同合成方法制备具有不同孔径和功能的碳材料的重要工作。综述文章的内容包括:(i)沸石中微孔碳的硬模板合成;(ii)介孔硅中的介孔碳的硬模板合成;(iii)大孔碳的硬模板合成;和(iv)介孔碳的软模板合成。本综述旨在为功能性纳米多孔碳材料的未来发展提供硬模板和软模板方法的详细概述。