Walker Richard J
Isotope Geochemistry Laboratory, Department of Geology, University of Maryland, College Park, MD 20742, USA.
Geochem Perspect. 2016;5(1):1-145. doi: 10.7185/geochempersp.5.1. Epub 2016 Apr 1.
The siderophile, or iron-loving elements have many applications in the Earth and planetary sciences. In primitive meteorites, differences in the relative abundances of these elements are likely due to both nebular and parent body processes. In addition, some siderophile elements are also characterised by isotopically distinctive nucleosynthetic signatures. Thus, the relative abundances and isotopic compositions of these elements can be used to trace the genetics of primary planetary building blocks. Although these elements are largely concentrated in the metallic cores of differentiated planetary bodies, their absolute and relative abundances, as well as their isotopic compositions can also reveal important information regarding conditions of core formation and the chemical evolution of the silicate portions of the planetary bodies. The lithophile-siderophile nature of the radiogenic Hf-W system allow it to be used to place chronologic constraints on planetary core formation. The differing incompatibilities of the two elements in silicate systems further mean that the system can also be used to study early differentiation processes and subsequent efficiency of mixing in the silicate portions of differentiated bodies, including Earth. The abundances of siderophile elements in the terrestrial mantle are used to assess primary and secondary melting processes, and resulting metasomatic interactions. In addition, the Re-Os isotope system can, in some instances, be used to place chronologic constraints on when these processes occurred. The abundances of siderophile elements, and Os/Os and Os/Os ratios in the mantle sources of ocean island basalts can be used to place constraints on the age of recycled materials, and in some instances, the types of recycled materials present in these mantle domains.
亲铁元素,即爱铁元素,在地球科学和行星科学中有许多应用。在原始陨石中,这些元素相对丰度的差异可能是由星云过程和母体过程共同导致的。此外,一些亲铁元素还具有同位素独特的核合成特征。因此,这些元素的相对丰度和同位素组成可用于追溯原始行星构建块的成因。尽管这些元素主要集中在分异行星体的金属核中,但它们的绝对丰度和相对丰度以及同位素组成也能揭示有关核心形成条件和行星体硅酸盐部分化学演化的重要信息。放射性Hf-W体系的亲石-亲铁性质使其可用于对行星核心形成施加年代学限制。这两种元素在硅酸盐体系中不同的不相容性还意味着该体系也可用于研究早期分异过程以及分异天体(包括地球)硅酸盐部分随后的混合效率。地幔中亲铁元素的丰度用于评估原生和次生熔融过程以及由此产生的交代作用。此外,在某些情况下,Re-Os同位素体系可用于对这些过程发生的时间施加年代学限制。大洋岛玄武岩地幔源中亲铁元素的丰度以及Os/Os和Os/Os比值可用于对再循环物质的年龄施加限制,在某些情况下,还可用于限制这些地幔域中存在的再循环物质的类型。