Salević Ana, Prieto Cristina, Cabedo Luis, Nedović Viktor, Lagaron Jose Maria
Department of Food Technology and Biochemistry, Faculty of Agriculture, University of Belgrade, Nemanjina 6, 11080 Zemun, Belgrade, Serbia.
Novel Materials and Nanotechnology Group, Institute of Agrochemistry and Food Technology (IATA), Spanish Council for Scientific Research (CSIC), Calle Catedrático Agustín Escardino Benlloch 7, 46980 Paterna, Valencia, Spain.
Nanomaterials (Basel). 2019 Feb 15;9(2):270. doi: 10.3390/nano9020270.
In this study, novel active films made of poly(ε-caprolactone) (PCL) containing a solid dispersion of sage extract (SE) were developed by means of the electrospinning technique and subsequent annealing treatment. Initially, the antioxidant and antimicrobial potential of SE was confirmed. Thereafter, the effect of SE incorporation at different loading contents (5%, 10%, and 20%) on the physicochemical and functional properties of the films was evaluated. The films were characterized in terms of morphology, transparency, water contact angle, thermal stability, tensile properties, water vapor, and aroma barrier performances, as well as antioxidant and antimicrobial activities. Thin, hydrophobic films with good contact transparency were produced by annealing of the ultrathin electrospun fibers. Interestingly, the effect of SE addition on tensile properties and thermal stability of the films was negligible. In general, the water vapor and aroma permeability of the PCL-based films increased by adding SE to the polymer. Nevertheless, a strong 2,2-diphenyl-1-picrylhydrazyl (DPPH) free radical scavenging ability, and a strong activity against foodborne pathogens and were achieved by SE incorporation into PCL matrix. Overall, the obtained results suggest great potential of the here-developed PCL-based films containing SE in active food packaging applications with the role of preventing oxidation processes and microbial growth.
在本研究中,通过静电纺丝技术及后续退火处理,制备了含有鼠尾草提取物(SE)固体分散体的新型聚(ε-己内酯)(PCL)活性薄膜。首先,证实了SE的抗氧化和抗菌潜力。此后,评估了不同负载量(5%、10%和20%)的SE掺入对薄膜物理化学和功能特性的影响。对薄膜的形态、透明度、水接触角、热稳定性、拉伸性能、水蒸气和香气阻隔性能以及抗氧化和抗菌活性进行了表征。通过对超薄静电纺丝纤维进行退火处理,制备出具有良好接触透明度的疏水薄膜。有趣的是,SE添加对薄膜拉伸性能和热稳定性的影响可忽略不计。总体而言,向聚合物中添加SE会使基于PCL的薄膜的水蒸气和香气渗透性增加。然而,将SE掺入PCL基质中可实现较强的2,2-二苯基-1-苦基肼(DPPH)自由基清除能力以及对食源性病原体的强大活性。总体而言,所得结果表明,此处开发的含SE的基于PCL的薄膜在活性食品包装应用中具有巨大潜力,可起到防止氧化过程和微生物生长的作用。