CIC biomaGUNE Paseo de Miramón 182, E-20014 Donostia-San Sebastian, Spain.
Chem Commun (Camb). 2019 Mar 14;55(23):3319-3322. doi: 10.1039/c8cc06827e.
Arrays of one, two and four electron-transfer active [4Fe-4S] clusters were constructed on modular tetratricopeptide repeat protein scaffolds, with the number of clusters determined solely by the size of the scaffold. The constructs show reversible redox activity and transient charge stabilization necessary to facilitate charge transfer.
在模块化四肽重复蛋白支架上构建了一维、二维和四元电子转移活性[4Fe-4S]簇阵列，簇的数量仅由支架的大小决定。这些构建体表现出可逆的氧化还原活性和瞬态电荷稳定化，这对于促进电荷转移是必要的。
