Sau Samaresh Chandra, Mei Ruhuai, Struwe Julia, Ackermann Lutz
Institut für Organische und Biomolekulare Chemie, Georg-August-Universität Göttingen, Tammannstraße 2, 37077, Göttingen, Germany.
ChemSusChem. 2019 Jul 5;12(13):3023-3027. doi: 10.1002/cssc.201900378. Epub 2019 Apr 24.
Electrochemical oxidative C-H/N-H activations with isocyanides have been realized with a versatile cobalt catalyst. The widely applicable cobalt catalysis manifold further enabled electrooxidative C-H/N-H carbonylations with carbon monoxide under ambient conditions. The C-H functionalizations were efficiently realized with ample scope and outstanding functional group tolerance in a user-friendly undivided cell setup.
一种通用的钴催化剂实现了与异腈的电化学氧化C-H/N-H活化。这种广泛适用的钴催化体系进一步实现了在环境条件下用一氧化碳进行的电氧化C-H/N-H羰基化反应。在用户友好的无隔膜电池装置中，C-H官能化反应得以高效实现，底物范围广泛且对官能团具有出色的耐受性。
