Institut für Organische und Biomolekulare Chemie, Georg-August-Universität Göttingen, Tammannstraße 2, 37077, Göttingen, Germany.
Angew Chem Int Ed Engl. 2018 Feb 23;57(9):2383-2387. doi: 10.1002/anie.201712647. Epub 2018 Jan 17.
Electrochemistry enabled C-H/N-H functionalizations at room temperature by external oxidant-free cobalt catalysis. Thus, the sustainable cobalt electrocatalysis manifold proceeds with excellent levels of chemoselectivity and positional selectivity, and with ample scope, thus allowing electrochemical C-H activation under exceedingly mild reaction conditions at room temperature in water.
电化学通过无外部氧化剂钴催化实现室温下的 C-H/N-H 官能团化。因此，可持续的钴电催化多相反应具有优异的化学选择性和位置选择性，并且具有广泛的适用范围，从而允许在室温下在水中极其温和的反应条件下进行电化学 C-H 活化。
