Clarke Aimee K, Ho Hon E, Rossi-Ashton James A, Taylor Richard J K, Unsworth William P
Department of Chemistry, University of York, York, YO10 5DD, UK.
Chem Asian J. 2019 Jun 3;14(11):1900-1911. doi: 10.1002/asia.201900309. Epub 2019 Apr 25.
Indoles are amongst the most important classes of heteroaromatics in organic chemistry, commonly found in biologically active natural products and therapeutically useful compounds. The synthesis of indoles is therefore important and several methods for their synthesis that make use of silver(I) catalysts and reagents have been developed in recent years. This Minireview contains, to the best of our knowledge, a comprehensive coverage of silver-mediated indole forming reactions since the first reaction of this type was reported in 2004.
吲哚是有机化学中最重要的杂环芳烃类别之一,常见于具有生物活性的天然产物和具有治疗作用的化合物中。因此,吲哚的合成很重要,近年来已经开发了几种利用银(I)催化剂和试剂进行合成的方法。据我们所知,本综述全面涵盖了自2004年首次报道此类反应以来银介导的吲哚形成反应。