Challabi Ahmed Jaafar Hussein, Chieng Buong Woei, Ibrahim Nor Azowa, Ariffin Hidayah, Zainuddin Norhazlin
Department of Chemistry, Faculty of Science, Universiti Putra Malaysia, 43400 UPM Serdang, Selangor, Malaysia.
Materials Processing and Technology Laboratory, Institute of Advanced Technology, Universiti Putra Malaysia, 43400 UPM Serdang, Selangor, Malaysia.
Polymers (Basel). 2019 Mar 13;11(3):482. doi: 10.3390/polym11030482.
The effectiveness of superheated steam (SHS) as an alternative, eco-friendly treatment method to modify the surface of pineapple leaf fiber (PALF) for biocomposite applications was investigated. The aim of this treatment was to improve the interfacial adhesion between the fiber and the polymer. The treatment was carried out in an SHS oven for different temperatures (190⁻230 °C) and times (30⁻120 min). Biocomposites fabricated from SHS-treated PALFs and polylactic acid (PLA) at a weight ratio of 30:70 were prepared via melt-blending techniques. The mechanical properties, dimensional stability, scanning electron microscopy (SEM), and X-ray diffraction (XRD) for the biocomposites were evaluated. Results showed that treatment at temperature of 220 °C for 60 min gave the optimum tensile properties compared to other treatment temperatures. The tensile, flexural, and impact properties as well as the dimensional stability of the biocomposites were enhanced by the presence of SHS-treated PALF. The SEM analysis showed improvement in the interfacial adhesion between PLA and SHS-treated PALF. XRD analysis showed an increase in the crystallinity with the addition of SHS-PALF. The results suggest that SHS can be used as an environmentally friendly treatment method for the modification of PALF in biocomposite production.
研究了过热蒸汽(SHS)作为一种替代的、环保的处理方法,用于改性菠萝叶纤维(PALF)表面以用于生物复合材料应用的有效性。该处理的目的是改善纤维与聚合物之间的界面粘附力。处理在SHS烘箱中于不同温度(190⁻230 °C)和时间(30⁻120分钟)下进行。通过熔融共混技术制备了由SHS处理的PALF和聚乳酸(PLA)以30:70的重量比制成的生物复合材料。对生物复合材料的力学性能、尺寸稳定性、扫描电子显微镜(SEM)和X射线衍射(XRD)进行了评估。结果表明,与其他处理温度相比,在220 °C下处理60分钟可获得最佳拉伸性能。SHS处理的PALF的存在增强了生物复合材料的拉伸、弯曲和冲击性能以及尺寸稳定性。SEM分析表明PLA与SHS处理的PALF之间的界面粘附力有所改善。XRD分析表明,添加SHS-PALF后结晶度增加。结果表明,SHS可作为生物复合材料生产中改性PALF的一种环保处理方法。