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通过熔融共混技术制备过热蒸汽处理黄麻与聚乳酸生物复合材料二元共混物及其增容作用

Manufacturing and compatibilization of binary blends of superheated steam treated jute and poly (lactic acid) biocomposites by melt-blending technique.

作者信息

Alim Md Abdul, Moniruzzaman Md, Hossain Md Muzaher, Repon Md Reazuddin, Hossain Ismail, Jalil Mohammad Abdul

机构信息

Department of Textile Engineering, Khulna University of Engineering & Technology, Khulna 9203, Bangladesh.

ZR Research Institute for Advanced Materials, Sherpur 2100, Bangladesh.

出版信息

Heliyon. 2022 Jul 13;8(8):e09923. doi: 10.1016/j.heliyon.2022.e09923. eCollection 2022 Aug.

Abstract

This work investigated the effect of superheated steam (SHS) jute fiber and poly (lactic acid) (PLA) having a weight proportion of 30:70 which were synthesized using the melt blending method. The goal of this treatment was to boost up the fiber-polymer interfacial linkage. The action was conducted in a superheated steam oven at various times (30-120 min) and temperatures (170-220 °C). The biocomposites were assessed in terms of mechanical characteristics, dimensional stability and morphological properties. Compared to different treatment temperatures, the results showed that treatment at 210 °C for 60 min offered the best tensile characteristics. Because of the presence of SHS-Jute, the tensile, impact, bending and dimensional stability of the bio-composites have been improved. The FTIR and SEM study revealed progress in the interfacial linkage between SHS-Jute and PLA. This interfacial link improves the bending strength of SHS-Jute-PLA biocomposites by about 15.64%. X-ray diffraction (XRD) investigation also showed an elevation in the crystalline structure with the incorporation of SHS-Jute. The degradation tests of the biocomposite were carried out in deionized water. SHS treatment reduces hemicellulose contents in jute fiber which causes water uptake% reduction is 54% in SHS-Jute-PLA. The SHS-Jute-PLA biocomposite appeared with promising characteristics for utilization as a green and ecological substitute particle board material.

摘要

本研究采用熔融共混法,对重量比为30:70的过热蒸汽(SHS)黄麻纤维与聚乳酸(PLA)进行了研究。该处理的目的是增强纤维与聚合物之间的界面结合。该操作在过热蒸汽烘箱中于不同时间(30 - 120分钟)和温度(170 - 220°C)下进行。对生物复合材料的力学性能、尺寸稳定性和形态性能进行了评估。与不同的处理温度相比,结果表明在210°C下处理60分钟具有最佳的拉伸性能。由于存在SHS - 黄麻,生物复合材料的拉伸、冲击、弯曲和尺寸稳定性均得到了改善。傅里叶变换红外光谱(FTIR)和扫描电子显微镜(SEM)研究表明SHS - 黄麻与PLA之间的界面结合有所改善。这种界面结合使SHS - 黄麻 - PLA生物复合材料的弯曲强度提高了约15.64%。X射线衍射(XRD)研究还表明,加入SHS - 黄麻后晶体结构有所提高。生物复合材料的降解试验在去离子水中进行。SHS处理降低了黄麻纤维中的半纤维素含量,这使得SHS - 黄麻 - PLA的吸水率降低了54%。SHS - 黄麻 - PLA生物复合材料表现出作为绿色生态替代刨花板材料的良好应用前景。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d6ac/9364090/209cc6f98d64/gr1.jpg

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