Department of Bioprocess Technology, Faculty of Biotechnology and Biomolecular Sciences, Universiti Putra Malaysia, Serdang 43400 UPM, Selangor, Malaysia.
Molecules. 2013 Jul 30;18(8):9132-46. doi: 10.3390/molecules18089132.
In this study, oil palm mesocarp fiber (OPMF) was treated with superheated steam (SHS) in order to modify its characteristics for biocomposite applications. Treatment was conducted at temperatures 190-230 °C for 1, 2 and 3 h. SHS-treated OPMF was evaluated for its chemical composition, thermal stability, morphology and crystallinity. OPMF treated at 230 °C exhibited lower hemicellulose content (9%) compared to the untreated OPMF (33%). Improved thermal stability of OPMF was found after the SHS treatment. Moreover, SEM and ICP analyses of SHS-treated OPMF showed that silica bodies were removed from OPMF after the SHS treatment. XRD results exhibited that OPMF crystallinity increased after SHS treatment, indicating tougher fiber properties. Hemicellulose removal makes the fiber surface more hydrophobic, whereby silica removal increases the surface roughness of the fiber. Overall, the results obtained herewith suggested that SHS is an effective treatment method for surface modification and subsequently improving the characteristics of the natural fiber. Most importantly, the use of novel, eco-friendly SHS may contribute to the green and sustainable treatment for surface modification of natural fiber.
在这项研究中,为了将油棕中果皮纤维(OPMF)的特性加以修饰以应用于生物复合材料,采用过热蒸汽(SHS)对其进行了处理。处理温度为 190-230°C,时间为 1、2 和 3 小时。对 SHS 处理后的 OPMF 的化学成分、热稳定性、形态和结晶度进行了评估。与未处理的 OPMF(33%)相比,在 230°C 下处理的 OPMF 的半纤维素含量(9%)较低。经过 SHS 处理后,OPMF 的热稳定性得到了提高。此外,对 SHS 处理后的 OPMF 的 SEM 和 ICP 分析表明,经过 SHS 处理后,OPMF 中的硅体被去除。XRD 结果表明,经过 SHS 处理后,OPMF 的结晶度增加,表明纤维的性能更加坚韧。半纤维素的去除使纤维表面更加疏水,而硅体的去除则增加了纤维的表面粗糙度。总的来说,这些结果表明,SHS 是一种有效的表面改性处理方法,可以改善天然纤维的特性。最重要的是,新型环保的 SHS 的使用可能有助于实现天然纤维表面改性的绿色和可持续处理。