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二氧化钛纳米粒子/碳纳米管/低密度聚乙烯杂化纳米复合薄膜的热性能

Thermal Properties of TiO₂NP/CNT/LDPE Hybrid Nanocomposite Films.

作者信息

Zagho Moustafa M, AlMaadeed Mariam Al Ali, Majeed Khaliq

机构信息

Materials Science and Technology Program, College of Arts and Sciences, Qatar University, Doha 2713, Qatar.

Center for Advanced Materials, Qatar University, Doha 2713, Qatar.

出版信息

Polymers (Basel). 2018 Nov 15;10(11):1270. doi: 10.3390/polym10111270.


DOI:10.3390/polym10111270
PMID:30961195
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC6401859/
Abstract

This work aims to investigate the effect of hybrid filler concentration on the thermal stability of low-density polyethylene (LDPE) matrices. LDPE-based composite films were synthesized by melt mixing, followed by compression molding, to study the influence of titanium oxide nanoparticles (TONPs) and/or multi-walled carbon nanotubes (CNTs) on the thermal properties of LDPE matrices. Fourier transform infrared (FTIR) spectroscopy confirmed the slight increase in the band intensities after TONP addition and a remarkable surge after the incorporation of CNTs. The value of crystallization temperature () was not modified after incorporating TONPs, while an enhancement was observed after adding the hybrid fillers. The melting temperature () was not changed after introducing the CNTs and CNT/TONP hybrid fillers. The percentage crystallinity ( %) was increased by 4% and 6%, after incorporating 1 wt % and 3 wt % CNTs, respectively. The TONP incorporation did not modify the %. Moreover, thermal gravimetric analysis (TGA) thermograms confirmed the increased thermal stability after introducing CNTs and hybrid fillers compared to TONP incorporation.

摘要

本工作旨在研究混合填料浓度对低密度聚乙烯(LDPE)基体热稳定性的影响。通过熔融共混,随后进行压缩成型,合成了基于LDPE的复合薄膜,以研究氧化钛纳米颗粒(TONPs)和/或多壁碳纳米管(CNTs)对LDPE基体热性能的影响。傅里叶变换红外(FTIR)光谱证实,添加TONPs后谱带强度略有增加,而加入CNTs后显著增强。加入TONPs后结晶温度()的值未改变,而添加混合填料后观察到有所提高。引入CNTs和CNT/TONP混合填料后,熔点温度()未发生变化。分别加入1 wt%和3 wt%的CNTs后,结晶度(%)提高了4%和6%。加入TONPs并未改变%。此外,热重分析(TGA)热谱图证实,与加入TONPs相比,引入CNTs和混合填料后热稳定性提高。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/175d/6401859/dee98219d5d5/polymers-10-01270-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/175d/6401859/bb0f05942900/polymers-10-01270-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/175d/6401859/879303cdbcc7/polymers-10-01270-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/175d/6401859/2f7c399b604a/polymers-10-01270-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/175d/6401859/a2b228c5623d/polymers-10-01270-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/175d/6401859/dee98219d5d5/polymers-10-01270-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/175d/6401859/bb0f05942900/polymers-10-01270-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/175d/6401859/879303cdbcc7/polymers-10-01270-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/175d/6401859/2f7c399b604a/polymers-10-01270-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/175d/6401859/a2b228c5623d/polymers-10-01270-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/175d/6401859/dee98219d5d5/polymers-10-01270-g005.jpg

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引用本文的文献

[1]
Synergy of Hybrid Fillers for Emerging Composite and Nanocomposite Materials-A Review.

Polymers (Basel). 2024-7-3

[2]
Model Progress for Tensile Power of Polymer Nanocomposites Reinforced with Carbon Nanotubes by Percolating Interphase Zone and Network Aspects.

Polymers (Basel). 2020-5-2

[3]
Analysis of the Connecting Effectiveness of the Interphase Zone on the Tensile Properties of Carbon Nanotubes (CNT) Reinforced Nanocomposite.

Polymers (Basel). 2020-4-13

[4]
Study on the Effects of the Interphase Region on the Network Properties in Polymer Carbon Nanotube Nanocomposites.

Polymers (Basel). 2020-1-10

[5]
Calculation of the Electrical Conductivity of Polymer Nanocomposites Assuming the Interphase Layer Surrounding Carbon Nanotubes.

Polymers (Basel). 2020-2-11

[6]
Development of Expanded Takayanagi Model for Tensile Modulus of Carbon Nanotubes Reinforced Nanocomposites Assuming Interphase Regions Surrounding the Dispersed and Networked Nanoparticles.

Polymers (Basel). 2020-1-17

[7]
Simulation of Percolation Threshold, Tunneling Distance, and Conductivity for Carbon Nanotube (CNT)-Reinforced Nanocomposites Assuming Effective CNT Concentration.

Polymers (Basel). 2020-1-5

[8]
A perspective on magnetic core-shell carriers for responsive and targeted drug delivery systems.

Int J Nanomedicine. 2019-3-6

[9]
Sputtering of Electrospun Polymer-Based Nanofibers for Biomedical Applications: A Perspective.

Nanomaterials (Basel). 2019-1-8

本文引用的文献

[1]
PES/POSS Soluble Veils as Advanced Modifiers for Multifunctional Fiber Reinforced Composites.

Polymers (Basel). 2017-7-13

[2]
Flexible Pressure Sensor Based on PVDF Nanocomposites Containing Reduced Graphene Oxide-Titania Hybrid Nanolayers.

Polymers (Basel). 2017-1-26

[3]
The Rediscovery of POSS: A Molecule Rather than a Filler.

Polymers (Basel). 2018-8-11

[4]
Recent Overviews in Functional Polymer Composites for Biomedical Applications.

Polymers (Basel). 2018-7-4

[5]
Recent advances in functional nanostructures as cancer photothermal therapy.

Int J Nanomedicine. 2018-5-17

[6]
Polymer-Based Electrospun Nanofibers for Biomedical Applications.

Nanomaterials (Basel). 2018-4-20

[7]
Stretchable Electrospun PVDF-HFP/Co-ZnO Nanofibers as Piezoelectric Nanogenerators.

Sci Rep. 2018-1-15

[8]
Effects on the Thermo-Mechanical and Crystallinity Properties of Nylon 6,6 Electrospun Fibres Reinforced with One Dimensional (1D) and Two Dimensional (2D) Carbon.

Materials (Basel). 2013-8-14

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