Zagho Moustafa M, AlMaadeed Mariam Al Ali, Majeed Khaliq
Materials Science and Technology Program, College of Arts and Sciences, Qatar University, Doha 2713, Qatar.
Center for Advanced Materials, Qatar University, Doha 2713, Qatar.
Polymers (Basel). 2018 Nov 15;10(11):1270. doi: 10.3390/polym10111270.
This work aims to investigate the effect of hybrid filler concentration on the thermal stability of low-density polyethylene (LDPE) matrices. LDPE-based composite films were synthesized by melt mixing, followed by compression molding, to study the influence of titanium oxide nanoparticles (TONPs) and/or multi-walled carbon nanotubes (CNTs) on the thermal properties of LDPE matrices. Fourier transform infrared (FTIR) spectroscopy confirmed the slight increase in the band intensities after TONP addition and a remarkable surge after the incorporation of CNTs. The value of crystallization temperature () was not modified after incorporating TONPs, while an enhancement was observed after adding the hybrid fillers. The melting temperature () was not changed after introducing the CNTs and CNT/TONP hybrid fillers. The percentage crystallinity ( %) was increased by 4% and 6%, after incorporating 1 wt % and 3 wt % CNTs, respectively. The TONP incorporation did not modify the %. Moreover, thermal gravimetric analysis (TGA) thermograms confirmed the increased thermal stability after introducing CNTs and hybrid fillers compared to TONP incorporation.
本工作旨在研究混合填料浓度对低密度聚乙烯(LDPE)基体热稳定性的影响。通过熔融共混,随后进行压缩成型,合成了基于LDPE的复合薄膜,以研究氧化钛纳米颗粒(TONPs)和/或多壁碳纳米管(CNTs)对LDPE基体热性能的影响。傅里叶变换红外(FTIR)光谱证实,添加TONPs后谱带强度略有增加,而加入CNTs后显著增强。加入TONPs后结晶温度()的值未改变,而添加混合填料后观察到有所提高。引入CNTs和CNT/TONP混合填料后,熔点温度()未发生变化。分别加入1 wt%和3 wt%的CNTs后,结晶度(%)提高了4%和6%。加入TONPs并未改变%。此外,热重分析(TGA)热谱图证实,与加入TONPs相比,引入CNTs和混合填料后热稳定性提高。
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