Cai Xiaomin, Cui Xiuguo, Zu Lei, Zhang You, Gao Xing, Lian Huiqin, Liu Yang, Wang Xiaodong
College of Material Science and Engineering, Beijing Institute of Petrochemical Technology, Beijing 102617, China.
State Key Laboratory of Organic⁻Inorganic Composites, Beijing University of Chemical Technology, Beijing 100029, China.
Polymers (Basel). 2017 Jul 20;9(7):288. doi: 10.3390/polym9070288.
The cooperative effects between the PANI (polyaniline)/nano-NiO (nano nickel oxide) composite electrode material and redox electrolytes (potassium iodide, KI) for supercapacitor applications was firstly discussed in this article, providing a novel method to prepare nano-NiO by using β-cyelodextrin (β-CD) as the template agent. The experimental results revealed that the composite electrode processed a high specific capacitance (2122.75 F·g at 0.1 A·g in 0.05 M KI electrolyte solution), superior energy density (64.05 Wh·kg at 0.2 A·g in the two-electrode system) and excellent cycle performance (86% capacitance retention after 1000 cycles at 1.5 A·g). All those ultra-high electrical performances owe to the KI active material in the electrolyte and the PANI coated nano-NiO structure.
本文首次探讨了聚苯胺(PANI)/纳米氧化镍(nano-NiO)复合电极材料与用于超级电容器的氧化还原电解质(碘化钾,KI)之间的协同效应,提供了一种以β-环糊精(β-CD)为模板剂制备纳米氧化镍的新方法。实验结果表明,该复合电极在0.05 M KI电解质溶液中,在0.1 A·g时具有高比电容(2122.75 F·g),在两电极体系中,在0.2 A·g时具有优异的能量密度(64.05 Wh·kg)和出色的循环性能(在1.5 A·g下1000次循环后电容保持率为86%)。所有这些超高的电学性能归因于电解质中的KI活性材料和PANI包覆的纳米氧化镍结构。