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采用等离子体预处理和壳聚糖/硅氧烷聚酯涂层对聚乳酸织物进行表面改性以提高色强度

Surface Modification of Poly(lactic acid) Fabrics with Plasma Pretreatment and Chitosan/Siloxane Polyesters Coating for Color Strength Improvement.

作者信息

Wang Chee-Chan, Lin Li-Huei, Chen Chi-Wu, Lo Yu-Chun

机构信息

Department of Cosmetic Science, Vanung University, 1, Van Nung Road, Taoyuan 32056, Taiwan.

出版信息

Polymers (Basel). 2017 Aug 18;9(8):371. doi: 10.3390/polym9080371.

Abstract

As people in the 21st century become increasingly environmentally aware, environmentally friendly products have come into focus. As such, environmentally friendly textiles and eco-textiles have become an international trend in research and development. Poly(lactic acid) fiber, which is biodegradable, holds much promise, but it is difficult to deep dye. This study used chitosan, succine anhydride, siloxane, and polyethylene glycol to produce a series of chitosan/siloxane polyesters that have a hydrophilic component (chitosan) and a hydrophobic component (siloxane), and this chitosan/siloxane polyester can be coated on poly(lactic acid) fiber, which we had subjected to Argon plasma treatment to increase their antimicrobial properties and to increase the fibers dyeing efficiency. The study shows that, after the surface plasma treatment, longer PEG chain lengths resulted in higher K/S values. This result suggests that the surface plasma pretreatment and chitosan/siloxane polyesters coating showed that lower ∆E values result in more leveling dyeing of poly(lactic acid) fiber.

摘要

随着21世纪的人们环保意识日益增强,环保产品成为焦点。因此,环保纺织品和生态纺织品已成为国际研发趋势。聚乳酸纤维可生物降解,前景广阔,但难以进行深色染色。本研究使用壳聚糖、琥珀酸酐、硅氧烷和聚乙二醇制备了一系列具有亲水性成分(壳聚糖)和疏水性成分(硅氧烷)的壳聚糖/硅氧烷聚酯,这种壳聚糖/硅氧烷聚酯可涂覆在经过氩等离子体处理的聚乳酸纤维上,以提高其抗菌性能并提高纤维的染色效率。研究表明,表面等离子体处理后,聚乙二醇链长越长,K/S值越高。这一结果表明,表面等离子体预处理和壳聚糖/硅氧烷聚酯涂层表明,较低的∆E值会使聚乳酸纤维的染色更均匀。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9299/6418909/e3c25d9e488c/polymers-09-00371-sch001.jpg

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