Key Laboratory of Organic Polymer Photoelectric Materials, School of Science, Xijing University, Xi'an 710123, China.
School of Chemistry and Chemical Engineering/Key Laboratory for Green Processing of Chemical Engineering of Xinjiang Bingtuan, Shihezi University, Shihezi 832003, China.
Molecules. 2019 Apr 4;24(7):1325. doi: 10.3390/molecules24071325.
In the past decades, borylation reactions have received extensive research interest and have developed into effective tools in the synthesis of versatile organoboron compounds. Boranes and symmetrical diboron compounds are commonly utilized as borylating reagents in these transformations, especially in the borylation reactions of unsaturated bonds. More recently, several types of unsymmetrical diboron reagents have been synthesized and applied in these borylation reactions, allowing for complementary chemo- and regioselectivity. This review aimed to highlight the recent development in this rising research field, focusing on new reactivity and selectivity that originates from the use of these unsymmetrical diboron reagents.
在过去几十年中，硼化反应受到了广泛的研究关注，并已发展成为合成多功能有机硼化合物的有效工具。在这些转化中，常用硼烷和对称二硼化合物作为硼化试剂，特别是在不饱和键的硼化反应中。最近，已经合成了几种类型的不对称二硼试剂，并将其应用于这些硼化反应中，从而实现了互补的化学和区域选择性。本综述旨在强调这一新兴研究领域的最新发展，重点介绍使用这些不对称二硼试剂所带来的新反应性和选择性。
