Yang Lin, Zhao Yang, Zhang Qian, Yang Juekuan, Li Deyu
Department of Mechanical Engineering, Vanderbilt University, Nashville, TN 37235, USA.
Nanoscale. 2019 Apr 25;11(17):8196-8203. doi: 10.1039/c9nr01855g.
Heat conduction has been shown to be greatly suppressed in Si nanomeshes, which has attracted extensive attention for potential thermoelectric applications, yet the precise suppression mechanism remains to be fully understood. Attempting to further disclose the underlying mechanisms, we report on the thermal conductivity of the building block for nanomeshes, i.e., Si nanoribbons with fins attached to the two opposite sides. By expanding only the fin width while keeping both the period length and the backbone size constant, we observed an unexpected non-monotonic trend of the effective thermal conductivity normalized with the backbone cross-section. Further analysis showed that the corrected thermal conductivity extracted with appropriate consideration of the geometrical effect on diffusion followed a monotonically decreasing trend, reaching a maximum thermal conductivity reduction of 18% at 300 K for a ribbon with the maximum explored fin width of 430 nm, as compared to that of the straight ribbon of 66 nm backbone width. We attribute the thermal conductivity reduction to the thermal constriction resistance induced by the cross-section reduction between the fin and backbone sections. For ribbons with a larger fin width, the effective phonon mean free path is longer for phonons arriving at the constriction, which boosts the ballistic constriction resistance, i.e., Sharvin resistance, and leads to a lower thermal conductivity.
研究表明,硅纳米网中的热传导受到极大抑制,这在潜在的热电应用中引起了广泛关注,但其精确的抑制机制仍有待充分理解。为了进一步揭示其潜在机制,我们报告了纳米网构建单元的热导率,即两侧附着鳍片的硅纳米带的热导率。通过仅扩大鳍片宽度,同时保持周期长度和主干尺寸不变,我们观察到有效热导率与主干横截面归一化后的意外非单调趋势。进一步分析表明,适当考虑几何形状对扩散的影响后提取的修正热导率呈单调下降趋势,与主干宽度为66nm的直纳米带相比,对于鳍片宽度最大为430nm的纳米带,在300K时热导率最大降低了18%。我们将热导率的降低归因于鳍片和主干部分之间横截面减小所引起的热收缩电阻。对于鳍片宽度较大的纳米带,到达收缩处的声子的有效声子平均自由程更长,这增加了弹道收缩电阻,即沙文电阻,并导致更低的热导率。