Wang Da, Wei Wenwen, Lai Yanhua, Yang Xiangzheng, Li Shaojia, Jia Lianwen, Wu Di
College of Energy and Power Engineering, Shandong University, Jinan 250061, China.
Jinan Fruit Research Institute, All China Federation of Supply and Marketing Cooperatives, Jinan 250014, China.
J Anal Methods Chem. 2019 Mar 17;2019:2360631. doi: 10.1155/2019/2360631. eCollection 2019.
The quality of strawberry powder depends on the freshness of the fruit that produces the powder. Therefore, identifying whether the strawberry powder is made from freshly available, short-term stored, or long-term stored strawberries is important to provide consumers with quality-assured strawberry powder. Nevertheless, such identification is difficult by naked eyes, as the powder colours are very close. In this work, based on the measurement of near-infrared (NIR) spectroscopy and mid-infrared (MIR) spectra of strawberry powered, good classification results of 100.00% correct rates to distinguish whether the strawberry powder was made from freshly available or stored fruit was obtained. Furthermore, partial least squares regression and least squares support vector machines (LS-SVM) models were established based on NIR, MIR, and combination of NIR and MIR data with full variables or optimal variables of strawberry powder to predict the storage days of strawberries that produced the powder. Optimal variables were selected by successive projections algorithm (SPA), uninformation variable elimination, and competitive adaptive reweighted sampling, respectively. The best model was determined as the SPA-LS-SVM model based on MIR spectra, which had the residual prediction deviation (RPD) value of 11.198 and the absolute difference between root-mean-square error of calibration and prediction (AB_RMSE) value of 0.505. The results of this work confirmed the feasibility of using NIR and MIR spectroscopic techniques for rapid identification of strawberry powder made from freshly available and stored strawberry.
草莓粉的质量取决于用于制作该粉的水果的新鲜度。因此,辨别草莓粉是由新鲜可得、短期储存还是长期储存的草莓制成,对于为消费者提供质量有保证的草莓粉很重要。然而,由于粉末颜色非常相近,仅靠肉眼很难进行这种辨别。在这项工作中,基于对草莓粉的近红外(NIR)光谱和中红外(MIR)光谱的测量,获得了区分草莓粉是由新鲜可得还是储存过的水果制成的良好分类结果,正确率达100.00%。此外,基于NIR、MIR以及NIR和MIR数据结合草莓粉的全变量或最优变量建立了偏最小二乘回归和最小二乘支持向量机(LS-SVM)模型,以预测制作该粉的草莓的储存天数。最优变量分别通过连续投影算法(SPA)、无信息变量消除和竞争自适应重加权采样来选择。基于MIR光谱的SPA-LS-SVM模型被确定为最佳模型,其具有11.198的残差预测偏差(RPD)值和0.505的校准和预测均方根误差绝对差值(AB_RMSE)。这项工作的结果证实了使用NIR和MIR光谱技术快速鉴别由新鲜可得和储存过的草莓制成的草莓粉的可行性。