Li Dachao, Liu Hongzhong, Chen Bangdao, Niu Dong, Lei Biao, Ye Guoyong, Jiang Weitao, Shi Yongsheng, Yin Lei, Lai Guoquan
State Key Laboratory for Manufacturing Systems Engineering, Xi'an Jiaotong University, Xi'an 710049, China.
Materials (Basel). 2019 Apr 16;12(8):1244. doi: 10.3390/ma12081244.
Graphene oxide (GO) was prepared using metal-catalyzed crystallization of amorphous carbon on a carbon fiber surface to improve the mechanical properties of the carbon fiber (CF). The deposited GO was used for repairing of surface structure defects on CF, thereby improving the tensile strength and interfacial strength force of CF. The grown morphology of GO and the changes in CF surface microstructure before and after remediation were investigated in detail by scanning tunneling microscopy and Raman spectroscopy. The effects of surface repair on the mechanical properties of the CF and the resulting composites were investigated systematically. The results of scanning tunneling microscopy show that the graphene oxide formed on the surface of carbon fiber present uniform dispersion. Raman spectroscopy curves indicate that CF successfully remediated the defects in the CF surface. The results of mechanical properties testing show that such a remediation method could significantly enhance the tensile strength of CF and increase the interfacial strength versus raw fibers; that is, the tensile strength of CF was enhanced by 42% and the interfacial strength by 33.7%.
通过在碳纤维表面进行金属催化的无定形碳结晶来制备氧化石墨烯(GO),以改善碳纤维(CF)的机械性能。沉积的GO用于修复CF表面的结构缺陷,从而提高CF的拉伸强度和界面强度。通过扫描隧道显微镜和拉曼光谱详细研究了GO的生长形态以及修复前后CF表面微观结构的变化。系统研究了表面修复对CF及其复合材料机械性能的影响。扫描隧道显微镜结果表明,在碳纤维表面形成的氧化石墨烯呈现均匀分散。拉曼光谱曲线表明CF成功修复了CF表面的缺陷。机械性能测试结果表明,这种修复方法可以显著提高CF的拉伸强度,并提高相对于原纤维的界面强度;即CF的拉伸强度提高了42%,界面强度提高了33.7%。