Faour Lara, Adam Catherine, Gautier Christelle, Goeb Sébastien, Allain Magali, Levillain Eric, Canevet David, Sallé Marc
Laboratoire MOLTECH-Anjou, UMR CNRS 6200, UNIV Angers, SFR MATRIX, 2 Bd Lavoisier, 49045 Angers Cedex, France.
Chem Commun (Camb). 2019 May 14;55(40):5743-5746. doi: 10.1039/c9cc02498k.
Tetrathiafulvalene redox units were grafted at both extremities of an oligopyridine-dicarboxamide foldamer through a straightforward copper-catalyzed azide-alkyne cycloaddition. The present work demonstrates that the hybridization equilibrium of foldamers can be tuned through redox stimulations.
通过直接的铜催化叠氮化物-炔烃环加成反应，四硫富瓦烯氧化还原单元被接枝到一个寡吡啶-二羧酰胺折叠体的两端。目前的工作表明，折叠体的杂交平衡可以通过氧化还原刺激来调节。
