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细菌纤维素膜与壳聚糖和聚乙烯醇的复合:机械和阻隔性能评估。

Characterization of bacterial cellulose films combined with chitosan and polyvinyl alcohol: Evaluation of mechanical and barrier properties.

机构信息

Instituto Politécnico Nacional, CICATA Unidad Querétaro, Cerro Blanco No. 141, Colinas del Cimatario, Querétaro 76090, Mexico; Department of Analytical Chemistry, Faculty of Veterinary, University of Santiago de Compostela, 27002 Lugo, Spain.

Instituto Politécnico Nacional, CICATA Unidad Querétaro, Cerro Blanco No. 141, Colinas del Cimatario, Querétaro 76090, Mexico.

出版信息

Carbohydr Polym. 2019 Jul 15;216:72-85. doi: 10.1016/j.carbpol.2019.03.093. Epub 2019 Mar 30.

Abstract

Bacterial cellulose (BC) produced by Komagataeibacter xylinus is a biomaterial with a unique three-dimensional structure. To improve the mechanical properties and reinforce the BC films, they were immersed in polyvinyl alcohol (0-4%) and chitosan (0-1%) baths. Moisture content, mechanical properties and water vapour permeability were measured to assess the effect of polyvinyl alcohol and chitosan. The morphology, optical, structural and thermal properties were evaluated by scanning electron microscopy, spectral analysis, thermogravimetry and differential scanning calorimetry. Results showed that moisture content was significantly affected by the chitosan presence. Tensile strength values in the 20.76-41.65 MPa range were similar to those of synthetic polymer films. Percentage of elongation ranged from 2.28 to 21.82% and Young's modulus ranged from 1043.88 to 2247.82 MPa. The water vapour permeability (1.47 × 10-3.40 × 10 g/m s Pa) decreased with the addition of polyvinyl alcohol. The developed films own UV light barrier properties and optimal visual appearance.

摘要

细菌纤维素(BC)由木醋杆菌属产生,是一种具有独特三维结构的生物材料。为了提高机械性能并增强 BC 膜的强度,将其浸泡在聚乙烯醇(0-4%)和壳聚糖(0-1%)溶液中。通过测量水分含量、机械性能和水蒸气透过率来评估聚乙烯醇和壳聚糖的效果。通过扫描电子显微镜、光谱分析、热重分析和差示扫描量热法评估了形态、光学、结构和热性能。结果表明,壳聚糖的存在显著影响了水分含量。拉伸强度值在 20.76-41.65 MPa 范围内,与合成聚合物膜相似。伸长率百分比范围为 2.28-21.82%,杨氏模量范围为 1043.88-2247.82 MPa。水蒸气透过率(1.47×10-3.40×10 g/m s Pa)随聚乙烯醇的添加而降低。所开发的薄膜具有紫外线阻隔性能和最佳的视觉外观。

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