关于“量化等离子体光催化中的热载流子和热贡献”的评论
Comment on "Quantifying hot carrier and thermal contributions in plasmonic photocatalysis".
作者信息
Sivan Yonatan, Baraban Joshua, Un Ieng Wai, Dubi Yonatan
机构信息
Unit of Electro-Optics Engineering, Ben-Gurion University of the Negev, Beer-Sheva, Israel.
Ilse Katz Center for Nanoscale Science and Technology, Ben-Gurion University of the Negev, Beer-Sheva, Israel.
出版信息
Science. 2019 May 3;364(6439). doi: 10.1126/science.aaw9367.
Zhou (Reports, 5 October 2018, p. 69) claim to have proven dominance of "hot" electrons over thermal effects in plasmonic photocatalysis. We identify experimental flaws that caused overestimation of the hot carrier contribution. As an alternative interpretation, we fully reproduce their data using a purely thermal Arrhenius law with a fixed activation energy and intensity-dependent heating.
周（《报告》，2018年10月5日，第69页）声称已证明在等离子体光催化中“热”电子比热效应占主导地位。我们发现了导致高估热载流子贡献的实验缺陷。作为另一种解释，我们使用具有固定活化能和强度依赖性加热的纯热阿仑尼乌斯定律完全重现了他们的数据。
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