Li Weijiang, Zhang Xiang, Meng Ruilin, Yan Jianchang, Wang Junxi, Li Jinmin, Wei Tongbo
State Key Laboratory of Solid-State Lighting, Institute of Semiconductors, University of Chinese Academy of Sciences, Beijing 100083, China.
Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing 100049, China.
Micromachines (Basel). 2019 May 13;10(5):322. doi: 10.3390/mi10050322.
β-GaO, characterized with high n-type conductivity, little lattice mismatch with III-Nitrides, high transparency (>80%) in blue, and UVA (400-320 nm) as well as UVB (320-280 nm) regions, has great potential as the substrate for vertical structure blue and especially ultra violet LEDs (light emitting diodes). Large efforts have been made to improve the quality of III-Nitrides epilayers on β-GaO. Furthermore, the fabrication of vertical blue LEDs has been preliminarily realized with the best result that output power reaches to 4.82 W (under a current of 10 A) and internal quantum efficiency (IQE) exceeds 78% by different groups, respectively, while there is nearly no demonstration of UV-LEDs on β-GaO. In this review, with the perspective from materials to devices, we first describe the basic properties, growth method, as well as doping of β-GaO, then introduce in detail the progress in growth of GaN on (1 0 0) and (-2 0 1) β-GaO, followed by the epitaxy of AlGaN on gallium oxide. Finally, the advances in fabrication and performance of vertical structure LED (VLED) are presented.
β-GaO具有高n型导电性、与III族氮化物晶格失配小、在蓝光以及UVA(400 - 320纳米)和UVB(320 - 280纳米)区域具有高透明度(>80%)等特性,作为垂直结构蓝光尤其是紫外发光二极管(LED)的衬底具有巨大潜力。人们已付出巨大努力来提高β-GaO上III族氮化物外延层的质量。此外,不同研究小组已初步实现垂直结构蓝光LED的制造,最佳结果是输出功率达到4.82瓦(在10安电流下)且内量子效率(IQE)超过78%,而在β-GaO上几乎没有紫外LED的相关报道。在本综述中,我们从材料到器件的角度,首先描述β-GaO的基本特性、生长方法以及掺杂情况,接着详细介绍在(1 0 0)和(-2 0 1)β-GaO上生长GaN的进展,随后是在氧化镓上生长AlGaN的情况。最后,展示垂直结构LED(VLED)制造和性能方面的进展。