King Abdullah University of Science and Technology (KAUST) , Physical Sciences and Engineering Division, Thuwal 23955-6900, Saudi Arabia.
King Abdullah University of Science and Technology (KAUST) , Imaging and Characterization Core Lab, Thuwal 23955-6900, Saudi Arabia.
ACS Appl Mater Interfaces. 2017 Oct 4;9(39):34057-34063. doi: 10.1021/acsami.7b09584. Epub 2017 Sep 22.
We demonstrate a state-of-the-art high-efficiency GaN-based vertical light-emitting diode (VLED) grown on a transparent and conductive (-201)-oriented (β-GaO) substrate, obtained using a straightforward growth process that does not require a high-cost lift-off technique or complex fabrication process. The high-resolution scanning transmission electron microscopy (STEM) images confirm that we produced high quality upper layers, including a multiquantum well (MQW) grown on the masked β-GaO substrate. STEM imaging also shows a well-defined MQW without InN diffusion into the barrier. Electroluminescence (EL) measurements at room temperature indicate that we achieved a very high internal quantum efficiency (IQE) of 78%; at lower temperatures, IQE reaches ∼86%. The photoluminescence (PL) and time-resolved PL analysis indicate that, at a high carrier injection density, the emission is dominated by radiative recombination with a negligible Auger effect; no quantum-confined Stark effect is observed. At low temperatures, no efficiency droop is observed at a high carrier injection density, indicating the superior VLED structure obtained without lift-off processing, which is cost-effective for large-scale devices.
我们展示了一种基于 GaN 的高效率垂直发光二极管(VLED),该器件生长在透明导电的 (-201) 取向(β-GaO)衬底上,采用了简单的生长工艺,不需要昂贵的剥离技术或复杂的制造工艺。高分辨率扫描透射电子显微镜(STEM)图像证实,我们生产出了高质量的上层材料,包括在掩蔽的β-GaO 衬底上生长的多量子阱(MQW)。STEM 成像还显示了一个定义明确的 MQW,没有 InN 扩散到势垒中。室温下的电致发光(EL)测量表明,我们实现了非常高的内量子效率(IQE)为 78%;在较低温度下,IQE 达到约 86%。光致发光(PL)和时间分辨 PL 分析表明,在高载流子注入密度下,发射由辐射复合主导,不存在可忽略的俄歇效应;没有观察到量子限制斯塔克效应。在低温下,在高载流子注入密度下没有观察到效率下降,这表明在没有剥离处理的情况下获得了优越的 VLED 结构,这对于大规模器件来说是具有成本效益的。