Selective decontamination of the reactive air pollutant nitrous acid node-linker cooperativity in a metal-organic framework.

Nitrous acid (HONO) is a reservoir of NO and an emerging pollutant having direct impacts on air quality, both in- and outdoors, as well as on human health. In this work, the amine-functionalized metal-organic framework (MOF), UiO-66-NH, was investigated due to its potential to selectively decontaminate nitrous acid at environmentally relevant concentrations. UiO-66-NH proved to be effective in the removal of nitrous acid from a continuous gaseous stream. This is observed the formation of an aryl diazonium salt that subsequently converts to a phenol with a concomitant release of nitrogen gas. This process is preceded the formation of the nitrosonium cation (likely protonation from an acidic proton on the node). Thus, UiO-66-NH is capable of selectively converting the pollutant nitrous acid to benign products.