Department of Physical Chemistry, University of Geneva, 30 Quai Ernest-Ansermet, 1211 Geneva 4, Switzerland.
Donostia International Physics Center, Paseo Manuel de Lardizabal 4, 20018 Donostia, Spain.
Int J Mol Sci. 2019 Jul 16;20(14):3483. doi: 10.3390/ijms20143483.
Oxadizoles are heterocyclic ring systems that find application in different scientific disciplines, from medicinal chemistry to optoelectronics. Coordination with metals (especially the transition ones) proved to enhance the intrinsic characteristics of these organic ligands and many metal complexes of oxadiazoles showed attractive characteristics for different research fields. In this review, we provide a general overview on different metal complexes and polymers containing oxadiazole moieties, reporting the principal synthetic approaches adopted for their preparation and showing the variety of applications they found in the last 40 years.
噁二唑是一种杂环体系,在从药物化学到光电等不同科学领域都有应用。与金属(特别是过渡金属)的配位被证明可以增强这些有机配体的固有特性,并且许多噁二唑金属配合物表现出对不同研究领域的有吸引力的特性。在这篇综述中,我们提供了含噁二唑部分的不同金属配合物和聚合物的概述,报告了用于制备它们的主要合成方法,并展示了它们在过去 40 年中找到的各种应用。