Lamont-Doherty Earth Observatory, Columbia University, Palisades, New York 10964, USA; email:
Ann Rev Mar Sci. 2020 Jan 3;12:49-85. doi: 10.1146/annurev-marine-010318-095123. Epub 2019 Jul 23.
The biogeochemical cycles of trace elements and their isotopes (TEIs) constitute an active area of oceanographic research due to their role as essential nutrients for marine organisms and their use as tracers of oceanographic processes. Selected TEIs also provide diagnostic information about the physical, geological, and chemical processes that supply or remove solutes in the ocean. Many of these same TEIs provide information about ocean conditions in the past, as their imprint on marine sediments can be interpreted to reflect changes in ocean circulation, biological productivity, the ocean carbon cycle, and more. Other TEIs have been introduced as the result of human activities and are considered contaminants. The development and implementation of contamination-free methods for collecting and analyzing samples for TEIs revolutionized marine chemistry, revealing trace element distributions with oceanographically consistent features and new insights about the processes regulating them. Despite these advances, the volume and geographic coverage of high-quality TEI data by the end of the twentieth century were insufficient to constrain their global biogeochemical cycles. To accelerate progress in this field of research, marine geochemists developed a coordinated international effort to systematically study the marine biogeochemical cycles of TEIs-the GEOTRACES program. Following a decade of planning and implementation, GEOTRACES launched its main field effort in 2010. This review, roughly midway through the field program, summarizes the steps involved in designing the program, its management structure, and selected findings.
微量元素和其同位素的生物地球化学循环(TEIs)是海洋学研究的一个活跃领域,因为它们是海洋生物的必需营养物质,并且可用作海洋过程的示踪剂。选定的 TEIs 还提供了有关物理、地质和化学过程的诊断信息,这些过程为海洋提供或去除溶质。其中许多相同的 TEIs 提供了有关过去海洋条件的信息,因为它们在海洋沉积物中的印记可以解释海洋环流、生物生产力、海洋碳循环等方面的变化。其他 TEIs 是人类活动的结果,被认为是污染物。开发和实施用于收集和分析 TEIs 样品的无污染方法彻底改变了海洋化学,揭示了具有海洋学一致性特征的痕量元素分布,并对调节这些元素的过程有了新的认识。尽管取得了这些进展,但到 20 世纪末,高质量 TEI 数据的数量和地理覆盖范围仍不足以约束其全球生物地球化学循环。为了加速该研究领域的进展,海洋地球化学家们开展了一项协调一致的国际努力,以系统地研究微量元素和其同位素的海洋生物地球化学循环——GEOTRACES 计划。经过十年的规划和实施,GEOTRACES 于 2010 年开始了其主要的实地工作。本综述大致在实地计划进行到一半时,总结了该计划的设计、管理结构和选定发现的步骤。