Electrospun polyurethane/phytic acid nanofibrous membrane for high efficient removal of heavy metal ions.

Polyurethane (PU) nanofibers possess large specific surface area and excellent mechanical properties which have been used as the matrix for many applications. Phytic acid is the biocompatible and environment-friendly organic acid with excellent chelating ability of heavy metal ions due to it contains 6 phosphate groups. In this study, the PU/phytic acid nanofibrous membrane has been successfully produced by electrospinning which was used for Pb removal. Though phytic acid would improve the hydrophilicity and reduce the mechanical properties to a certain extent, the phytic acid-modified PU nanofibrous membrane still possessed excellent mechanical properties. The PU/phytic acid nanofibrous membrane achieved the highest adsorption capacity (136.52 mg/g) of Pb under the condition of the pH of Pb solution was 6 and the adsorption temperature and time were 20°C and 10 h which was over 6 times higher the unmodified one's (21.06 mg/g). These results demonstrated that the electrospun PU/phytic acid nanofibrous membrane could obtain high adsorption capacity of Pb and it would achieve the potential application in the fields of the removal of heavy metal ions.