迈向离子液体/金属有机框架复合材料的合理设计：离子间相互作用能的影响。
Toward Rational Design of Ionic Liquid/Metal-Organic Framework Composites: Effects of Interionic Interaction Energy.
作者信息
Nozari Vahid, Keskin Seda, Uzun Alper
机构信息
Department of Chemical and Biological Engineering and Koç University TÜPRAŞ Energy Center (KUTEM), Koç University, Rumelifeneri Yolu, 34450 Sariyer, Istanbul, Turkey.
出版信息
ACS Omega. 2017 Oct 11;2(10):6613-6618. doi: 10.1021/acsomega.7b01074. eCollection 2017 Oct 31.
One of the structural factors controlling the extent of interactions between ionic liquids (ILs) and metal-organic frameworks (MOFs) in IL/MOF composites is elucidated. Results showed that the thermal stability limits and adsorption performances of the IL/MOF composites can be tuned by the interionic interaction energy of bulk ILs, which can be probed spectroscopically via C2H infrared stretching frequency.
阐明了控制离子液体（ILs）与金属有机框架（MOFs）在IL/MOF复合材料中相互作用程度的结构因素之一。结果表明，IL/MOF复合材料的热稳定性极限和吸附性能可通过本体离子液体的离子间相互作用能进行调节，该相互作用能可通过C2H红外伸缩频率进行光谱探测。
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