Reusable Hollow Polymer Microreactors Incorporated with Anisotropic Nanoparticles for Catalysis Application.

We report a methodology to encapsulate gold nanorods (AuNRs) and gold bipyramids (AuBPs) into polyelectrolyte capsules for catalytic application. Microreactors (capsules with encapsulated NRs or BPs) were fabricated by sequential deposition of poly(allylamine hydrochloride) and dextran sulfate on modified sacrificial template, followed by core dissolution. AuNRs and AuBPs of size 25-30 nm were successfully encapsulated in the fabricated polyelectrolyte capsules and were stable and distributed uniformly in the interior. Fabricated microreactors were investigated as catalysts for the reduction of -nitrophenol to -aminophenol in the presence of sodium borohydride in aqueous phase. Reaction parameters such as order, conversion, and rate constants were estimated for microreactors and compared to free anisotropic nanoparticles in suspension. The reaction rate was higher for NRs in both free and capsule forms compared to BPs. Microreactors demonstrated excellent catalytic activity even after three times of use. Such capsules have high potential for use as microreactors in applications such as catalysis, drug delivery, imaging, and cancer chemo-photothermal therapy.