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科学仪器飞秒 X 射线实验(FXE):仪器和基本实验能力。

Scientific instrument Femtosecond X-ray Experiments (FXE): instrumentation and baseline experimental capabilities.

机构信息

Femtosecond X-ray Experiments Group, European XFEL, Holzkoppel 4, 22869 Schenefeld, Germany.

STFC Technology, Rutherford Appleton Laboratory, Didcot, Oxfordshire OX11 0QX, UK.

出版信息

J Synchrotron Radiat. 2019 Sep 1;26(Pt 5):1432-1447. doi: 10.1107/S1600577519006647. Epub 2019 Aug 9.

Abstract

The European X-ray Free-Electron Laser (EuXFEL) delivers extremely intense (>10 photons pulse and up to 27000 pulses s), ultrashort (<100 fs) and transversely coherent X-ray radiation, at a repetition rate of up to 4.5 MHz. Its unique X-ray beam parameters enable novel and groundbreaking experiments in ultrafast photochemistry and material sciences at the Femtosecond X-ray Experiments (FXE) scientific instrument. This paper provides an overview of the currently implemented experimental baseline instrumentation and its performance during the commissioning phase, and a preview of planned improvements. FXE's versatile instrumentation combines the simultaneous application of forward X-ray scattering and X-ray spectroscopy techniques with femtosecond time resolution. These methods will eventually permit exploitation of wide-angle X-ray scattering studies and X-ray emission spectroscopy, along with X-ray absorption spectroscopy, including resonant inelastic X-ray scattering and X-ray Raman scattering. A suite of ultrafast optical lasers throughout the UV-visible and near-IR ranges (extending up to mid-IR in the near future) with pulse length down to 15 fs, synchronized to the X-ray source, serve to initiate dynamic changes in the sample. Time-delayed hard X-ray pulses in the 5-20 keV range are used to probe the ensuing dynamic processes using the suite of X-ray probe tools. FXE is equipped with a primary monochromator, a primary and secondary single-shot spectrometer, and a timing tool to correct the residual timing jitter between laser and X-ray pulses.

摘要

欧洲 X 射线自由电子激光(EuXFEL)提供了极高强度 (>10 个光子脉冲,最高可达 27000 个脉冲/秒)、超短 (<100fs) 和横向相干的 X 射线辐射,重复频率高达 4.5MHz。其独特的 X 射线光束参数使得在飞秒 X 射线实验(FXE)科学仪器中能够进行超快光化学和材料科学的新颖和开创性实验。本文提供了当前实施的实验基线仪器的概述,以及在调试阶段的性能,并预览了计划的改进。FXE 的多功能仪器将前向 X 射线散射和 X 射线光谱技术的同时应用与飞秒时间分辨率相结合。这些方法最终将允许广泛应用广角 X 射线散射研究和 X 射线发射光谱学,以及 X 射线吸收光谱学,包括共振非弹性 X 射线散射和 X 射线拉曼散射。一套超短的紫外可见和近红外范围的超快光学激光器(在不久的将来将扩展到中红外范围),脉冲长度可达 15fs,与 X 射线源同步,用于引发样品中的动态变化。在 5-20keV 范围内的时滞硬 X 射线脉冲用于使用一系列 X 射线探测工具探测随后的动态过程。FXE 配备了一个主单色器、一个主和副单次光谱仪,以及一个定时工具,以校正激光和 X 射线脉冲之间的残余定时抖动。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/10df/6730617/ad822675118a/s-26-01432-fig1.jpg

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