Department of Chemistry, National Institute of Technology, Silchar, Assam, 788010, India.
Department of Chemistry, G.C. College, Silchar, Assam, 788004, India.
Sci Rep. 2019 Sep 10;9(1):12935. doi: 10.1038/s41598-019-49181-2.
Herein, we described a biogenic, additive fee, eco-friendly synthesized SnO-CNT nanohybrid as an efficient, re-collectable and reusable material for onsite water remediation. We demonstrated that the SnO-CNTs can provide a one stop solution for water remediation as it effectively accomplished the major treatment tasks like adsorption, catalytic transformation/degradation and disinfection. The structural, morphological, surface chemical compositions of the nanocomposite and the adsorption, catalytic and antimicrobial properties were investigated using common characterization and instrumental techniques. The results revealed the brilliant efficiency of SnO-CNT nanoadsorbent towards As (III) and a maximum Langmuir adsorption capacity of 106.95 mg/g was observed at high arsenite concentration (C = 1 mg/L). The nanoadsorbent was also found to be equally efficient in low arsenite concentration ranges (C = 100 μg/L) as it could bring down the arsenic concentration below maximum permissible limit. Moreover, using model pollutants like p-nitrophenol, Alizarin red S, Metronidazole, bacterial strains (Bacillus subtilis, Escherichia coli, Streptococcus pneumonia etc.), and fungal strains (Aspergillus niger and Candida albicans), the multifunctional capability of SnO-CNT towards water decontamination has been established. Our results suggested the promising potential of hierarchical nano-heterojunctions for engineering efficient water treatment processes.
在这里,我们描述了一种生物合成的、附加费的、环保的 SnO-CNT 纳米杂化材料,它是一种高效、可再收集和可重复使用的现场水修复材料。我们证明了 SnO-CNTs 可以为水修复提供一站式解决方案,因为它可以有效地完成主要的处理任务,如吸附、催化转化/降解和消毒。使用常见的表征和仪器技术研究了纳米复合材料的结构、形态、表面化学成分以及吸附、催化和抗菌性能。结果表明,SnO-CNT 纳米吸附剂对 As(III)具有出色的效率,在高亚砷酸盐浓度(C=1mg/L)下观察到最大的 Langmuir 吸附容量为 106.95mg/g。纳米吸附剂在低亚砷酸盐浓度范围内(C=100μg/L)同样有效,因为它可以将砷浓度降低到最大允许限度以下。此外,使用模型污染物,如对硝基苯酚、茜素红 S、甲硝唑、细菌菌株(枯草芽孢杆菌、大肠杆菌、肺炎链球菌等)和真菌菌株(黑曲霉和白色念珠菌),确立了 SnO-CNT 对水净化的多功能能力。我们的结果表明,分层纳米异质结具有用于工程高效水处理过程的巨大潜力。