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将铽配合物共价接枝到海藻酸盐水凝胶及其在铁和pH传感中的应用

Covalent Grafting Terbium Complex to Alginate Hydrogels and Their Application in Fe and pH Sensing.

作者信息

Zhang Zeyu, Liu Fengyi, Xu Quanqing, Zhu Han, Zhu Aixin, Kou Junfeng

机构信息

College of Chemistry and Chemical Engineering Yunnan Normal University Kunming 650500 China.

出版信息

Glob Chall. 2018 Nov 13;3(2):1800067. doi: 10.1002/gch2.201800067. eCollection 2019 Feb.

DOI:10.1002/gch2.201800067
PMID:31565360
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC6607234/
Abstract

Biocompatible luminescent hydrogels containing covalently linked terbium complexes with a macrocyclic ligand are prepared by a facile method. The environmentally friendly preparation procedure is carried out at room temperature using water as a solvent. These new hybrid materials can act as luminescent sensors to detect Fe with relative selectivity and high sensitivity. The hydrogels also show pH sensing with a wide range.

摘要

通过一种简便的方法制备了含有与大环配体共价连接的铽配合物的生物相容性发光水凝胶。该环保制备过程在室温下以水为溶剂进行。这些新型杂化材料可作为发光传感器，以相对选择性和高灵敏度检测铁。这些水凝胶还显示出宽范围的pH传感性能。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3c1b/6607234/b0d191c66da0/GCH2-3-na-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3c1b/6607234/11742e218d34/GCH2-3-na-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3c1b/6607234/07dd4b1275c1/GCH2-3-na-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3c1b/6607234/9ce43e89dc88/GCH2-3-na-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3c1b/6607234/289475ec6700/GCH2-3-na-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3c1b/6607234/b0d191c66da0/GCH2-3-na-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3c1b/6607234/11742e218d34/GCH2-3-na-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3c1b/6607234/07dd4b1275c1/GCH2-3-na-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3c1b/6607234/9ce43e89dc88/GCH2-3-na-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3c1b/6607234/289475ec6700/GCH2-3-na-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3c1b/6607234/b0d191c66da0/GCH2-3-na-g005.jpg

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Preparation and Properties of Transparent Ultrathin Lanthanide-Complex Films.
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