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一步法硅油注入型超滑涂层的冰面不附着性能:表面能、油和纳米颗粒含量的影响。

Icephobic performance of one-step silicone-oil-infused slippery coatings: Effects of surface energy, oil and nanoparticle contents.

机构信息

Department of Chemistry, University of Eastern Finland, P.O. Box 111, FI-80101 Joensuu, Finland.

Department of Chemistry, University of Eastern Finland, P.O. Box 111, FI-80101 Joensuu, Finland.

出版信息

J Colloid Interface Sci. 2020 Jan 15;558:251-258. doi: 10.1016/j.jcis.2019.09.119. Epub 2019 Sep 30.

Abstract

HYPOTHESIS

State-of-the-art superhydrophobic surfaces (SHSs) usually do not function in high humidity and frosty climate conditions. Lubricant-infused slippery surfaces (LISSs) with a homogeneous and ultraslippery surface are expected to be a reliable icephobic technique. Hence, the fabrication of simple and scalable bioinspired LISSs is important for practical applications.

EXPERIMENTS

Durable one-step LISSs consisting of silicone oil and polymer mixtures were fabricated. A grid map based on added oil and silica nanoparticles was developed to tune wettability, morphology, and slippery behavior of surfaces. A similar framework for ice adhesion of lubricant-infused coatings was also presented for the design of optimal icephobic materials.

FINDINGS

LISSs with slight hydrophobicity yield slippery properties, resulting in an order of magnitude lower ice adhesion compared to SHSs. The stable 20-w% silicone-oil-infused slippery coating with slight hydrophobicity and silica nanoparticles was found to be effective in anti-icing. The nanoparticles firmly anchor the oil overlayer and eliminate contamination by drying the surface. The LISSs made of polymers with surface energy ranging from 29 to 31 mJ/m show the potential to achieve low ice adhesion. As a result, the use of systematic frameworks highlights the role of material parameters. One-production strategy can be broadly used to design icephobic materials.

摘要

假设

最先进的超疏水表面(SHSs)通常无法在高湿度和结霜的气候条件下发挥作用。具有均匀和超滑表面的含润滑剂的光滑表面(LISSs)有望成为一种可靠的抗冰技术。因此,制造简单且可扩展的仿生 LISSs 对于实际应用非常重要。

实验

制备了由硅油和聚合物混合物组成的耐用一步法 LISSs。开发了基于添加油和二氧化硅纳米粒子的网格图,以调节表面的润湿性、形态和滑动性能。还提出了用于润滑涂层冰附着力的类似框架,用于设计最佳的抗冰材料。

发现

具有轻微疏水性的 LISSs 产生滑动性能,与 SHSs 相比,冰附着力降低了一个数量级。发现具有轻微疏水性和二氧化硅纳米粒子的稳定 20-w%硅油注入滑爽涂层在抗冰方面非常有效。纳米粒子牢固地固定油覆盖层并通过干燥表面消除污染。表面能在 29 至 31 mJ/m 之间的聚合物制成的 LISSs 显示出实现低冰附着力的潜力。因此,系统框架的使用突出了材料参数的作用。一次生产策略可以广泛用于设计抗冰材料。

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