RWTH Aachen University, Institute of Organic Chemistry, Landoltweg 1, 52074 Aachen, Germany.
Chem Commun (Camb). 2019 Nov 4;55(85):12825-12828. doi: 10.1039/c9cc06830a. Epub 2019 Oct 9.
Herein, we report on rhodium catalysed carbene transfer reactions of diazoesters with diselenides that result in the formal insertion reaction of the carbene fragment into the Se-Se bond to give seleno-ketals in up to 96% yield (35 examples) via an ionic mechanism.
在此，我们报告了铑催化的重氮酯与二硒醚的卡宾转移反应，该反应导致卡宾片段通过离子机理正式插入 Se-Se 键中，以高达 96%的收率（35 个实例）得到硒代缩醛。
