区域和立体选择性铜催化环丙硅烷的碳金属化反应。
Regio- and Diastereoselective Copper-Catalyzed Carbometalation of Cyclopropenylsilanes.
机构信息
Schulich Faculty of Chemistry , Technion - Israel Institute of Technology , Technion City, Haifa , 3200009 , Israel.
出版信息
Org Lett. 2019 Nov 15;21(22):9162-9165. doi: 10.1021/acs.orglett.9b03531. Epub 2019 Nov 1.
PMID:31674787
Abstract
We therein report a regio- and diastereoselective copper-catalyzed carbometalation of enantioenriched readily available cyclopropenylsilanes as a synthetic tool to access a large family of stereodefined fully-(hexa)-substituted cyclopropanes.
摘要
我们在此报告了一种对映富集的易得环丙基硅烷的区域和立体选择性铜催化碳金属化反应，这是一种合成工具，可用于构建一大类具有立体定义的全（六）取代的环丙烷。
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