Scalliet Camille, Berthier Ludovic, Zamponi Francesco
Laboratoire Charles Coulomb (L2C), Université de Montpellier, CNRS, 34095, Montpellier, France.
Laboratoire de Physique de l'Ecole Normale Supérieure, ENS, Université PSL, CNRS, Sorbonne Université, Université de Paris, 75005, Paris, France.
Nat Commun. 2019 Nov 8;10(1):5102. doi: 10.1038/s41467-019-13010-x.
The nature of defects in amorphous materials, analogous to vacancies and dislocations in crystals, remains elusive. Here, we explore their nature in a three-dimensional microscopic model glass-former that describes granular, colloidal, atomic and molecular glasses by changing the temperature and density. We find that all glasses evolve in a very rough energy landscape, with a hierarchy of barrier sizes corresponding to both localized and delocalized excitations. Collective excitations dominate in the jamming regime relevant for granular and colloidal glasses. By moving gradually to larger densities describing atomic and molecular glasses, the system crosses over to a regime dominated by localized defects and relatively simpler landscapes. We quantify the energy and temperature scales associated to these defects and their evolution with density. Our results pave the way to a systematic study of low-temperature physics in a broad range of physical conditions and glassy materials.
非晶态材料中的缺陷本质,类似于晶体中的空位和位错,仍然难以捉摸。在这里,我们在一个三维微观模型玻璃形成体中探索它们的本质,该模型通过改变温度和密度来描述颗粒、胶体、原子和分子玻璃。我们发现,所有玻璃都在非常粗糙的能量景观中演化,具有对应于局域和非局域激发的一系列势垒大小。集体激发在与颗粒和胶体玻璃相关的堵塞状态中占主导地位。通过逐渐移动到描述原子和分子玻璃的更大密度,系统转变到一个由局域缺陷和相对简单的景观主导的状态。我们量化了与这些缺陷相关的能量和温度尺度以及它们随密度的演化。我们的结果为在广泛的物理条件和玻璃态材料中系统研究低温物理铺平了道路。