Department of Nanomaterials and Application Technology, Center of Innovative and Applied Bioprocessing (CIAB), Sector 81 (Knowledge City), S.A.S. Nagar, 140306, Punjab, India.
J Mater Chem B. 2020 Jan 14;8(2):260-269. doi: 10.1039/c9tb01569h. Epub 2019 Dec 4.
Agri-biomass derived lignin is one of the most abundant natural nontoxic organic polymers. However, a major portion of lignin is underutilized, which is being left in the fields or thrown into rivers, causing waste accumulation. Utilization of the low-cost biomass-derived lignin serves a dual purpose by reducing agri-waste and by converting it into value-added materials. Here we describe the valorization of agri-biomass based lignin via its direct utilization in the green and one-step synthesis of zinc oxide nanocomposites. Lignin offered an easy and sustainable synthesis of nanocomposites in a water-ethanol mixture without the need to use any toxic material. The lignin derived nanomaterials showed excellent potential as antioxidant, UV-blocking and antimicrobial agents due to the synergistic effect of lignin and zinc oxide. Further, these nanocomposites were incorporated as an additive into a commonly used body cream to impart UV-blocking and antimicrobial properties. This one-step, cost-effective and green synthesis technique of lignin derived zinc oxide nanocomposites not only contributes to agro-waste reduction, but at the same time helps in the production of value-added materials.
农业生物质衍生木质素是最丰富的天然无毒有机聚合物之一。然而,大部分木质素未得到充分利用,它们被留在田间或被扔进河流中,造成浪费堆积。利用低成本的生物质衍生木质素不仅可以减少农业废弃物,还可以将其转化为高附加值材料,从而实现双重目的。在这里,我们通过直接利用农业生物质衍生木质素在绿色和一步法合成氧化锌纳米复合材料方面描述了其增值用途。木质素在水-乙醇混合物中提供了一种简单且可持续的纳米复合材料合成方法,无需使用任何有毒材料。由于木质素和氧化锌的协同作用,木质素衍生的纳米材料表现出作为抗氧化剂、紫外线阻断剂和抗菌剂的优异潜力。此外,这些纳米复合材料被掺入一种常用的身体乳中,以赋予其紫外线阻断和抗菌性能。这种一步法、具有成本效益和绿色的木质素衍生氧化锌纳米复合材料的合成技术不仅有助于减少农业废弃物,同时还有助于生产高附加值材料。