Pentagram-Shaped Ag@Pt Core-Shell Nanostructures as High-Performance Catalysts for Formaldehyde Detection.

High-performance HCHO sensors are of great importance in various application fields such as indoor air quality assessments. Herein, bimetallic Ag-Pt nanoparticles are synthesized as high-performance catalysts for ZnO-based gas sensors. Spherical aberration (Cs)-corrected transmission electron microscopy images with atomic resolution clearly indicate that the prepared nanoparticles exhibit a novel Ag@Pt core-shell nanostructure with a pentagram shape. For high-performance HCHO sensor construction, integrated micro-electrodes are first fabricated with the microelectromechanical system (MEMS) technology. Then, the hydrothermal route is used to self-assemble well-aligned ZnO nanowire arrays onto the sensing microregion. After that, the pentagram-shaped Ag@Pt nanoparticles are loaded onto the surface of ZnO nanowires with the inkjet printing technique to form MEMS sensors with Ag@Pt@ZnO as the sensing material. The thoroughly sensing experiments indicate that the Ag@Pt nanoparticles exhibit satisfied catalytic activation to HCHO molecules. The experimental observed detection limit of our sensor to HCHO reaches the parts per billion level. To elucidate the HCHO-sensing mechanism, the online mass spectrum (online MS) is utilized to analyze the components of exhaust gas stream of HCHO flowing through the Ag@Pt@ZnO material. The online MS indicates that with the Ag@Pt catalyst, HCHO molecules are partially oxidized to HCOOH molecules at low temperatures and are completely oxidized to CO molecules at high temperatures.