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一种用于水相介质中铜(I)的基于反应的高选择性双光子探针。

A Highly Selective Reaction-Based Two-Photon Probe for Copper(I) in Aqueous Media.

作者信息

Maity Debabrata, Sarkar Bidyut, Maiti Sudipta, Govindaraju T

机构信息

Bioorganic Chemistry Laboratory, New Chemistry Unit, Jawaharlal Nehru Centre for Advanced Scientific Research, Jakkur P.O., Bangalore 560064 (India), Fax: (+91) 80-22082627.

Department of Chemical Sciences, Tata Institute of Fundamental Research, Homi Bhabha Road, Colaba, Mumbai 400005 (India).

出版信息

Chempluschem. 2013 Aug;78(8):785-788. doi: 10.1002/cplu.201300089. Epub 2013 Jun 11.

Abstract

Out of the blue: A reaction-based two-photon probe XanCu is reported for the selective detection of Cu in reducing aqueous environments. Copper(I)-mediated oxidative benzylic ether (CO) bond cleavage offers "switch-on" detection of the metal ion.

摘要

意外发现

报道了一种基于反应的双光子探针XanCu,用于在还原性水性环境中选择性检测铜。铜(I)介导的氧化苄基醚(CO)键断裂实现了对金属离子的“开启”检测。

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