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基于双功能荧光探针的汞(II)和肼的区分检测。

Discriminative detection of mercury (II) and hydrazine using a dual-function fluorescent probe.

机构信息

Beijing Advanced Innovation Centre for Food Nutrition and Human Health, Beijing Key Laboratory of Flavour Chemistry, Beijing Technology and Business University, Beijing, China.

出版信息

Luminescence. 2020 Aug;35(5):754-762. doi: 10.1002/bio.3781. Epub 2020 Jan 30.

Abstract

A dual-function fluorescent probe (Probe 1) was developed for discriminative detection of Hg and N H . Probe 1 could discriminatively detect Hg and N H through two different reaction sites, with the mechanism for Probe 1 for Hg depending on a desulfurization reaction and for N H depending on the Schiff-base reaction. N H had minimal effect on Hg detection in dimethyl sulfoxide (DMSO)/H O solution, but Hg could interfere with N H detection in DMSO/buffer solution. Different concentrations of Hg and N H resulted in different blue shades of Probe 1 test strips, and the shade of blue was different with the same concentration of Hg or N H , as observed under ultraviolet light at 365 nm wavelength.

摘要

一种双功能荧光探针(探针 1)被开发用于区分检测 Hg 和 NH。探针 1 可以通过两个不同的反应位点来区分检测 Hg 和 NH,其检测 Hg 的机制依赖于脱硫反应,而检测 NH 则依赖于希夫碱反应。NH 对 DMSO/H2O 溶液中 Hg 检测的影响很小,但 Hg 可以干扰 DMSO/缓冲溶液中 NH 检测。不同浓度的 Hg 和 NH 导致探针 1 试条呈现不同的蓝色阴影,并且在 365nm 波长的紫外光下观察到,相同浓度的 Hg 或 NH 的蓝色阴影不同。

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