Performance of the emerging biochar on the stabilization of potentially toxic metals in smelter- and mining-contaminated soils.

Soil potentially toxic metals (PTMs) pollution caused by anthropogenic activities has become serious concern with respect to the crop safety production. In this study, an emerging biochar derived from kiwi pruning branches waste was employed as amendment aiming to evaluate its remediation potential on smelter- and mining-contaminated soils. The effect of biochar on the soil physicochemical properties, leachability, and chemical fractions acted on stabilization practice of PTMs in soil was investigated. The results showed that the addition of biochar increased the soil pH, cation exchange capacity, organic matter, and enzymatic activities (dehydrogenase, urease, and sucrase) but reduced the extraction toxicity of PTMs in both smelter (Fengxian, FX) and mining (Tongguan, TG) soils. The fraction analysis showed that the maximum reduction of exchangeable fraction of Cd, Zn, and Pb in the 4% biochar amended soils decreased by 11.1, 13.3, and 24.7% in FX soil and 7.67, 22.8, and 7.89% in TG soil, respectively, in comparison with to control (no biochar added). Additionally, the residual fraction of Cd, Zn, and Pb increased by 55.9, 7.14, and 11.0% in FX soil and 23.7, 5.86, and 10.0% in TG soil, respectively. The further greenhouse experiment showed that the Indian mustard (Brassica juncea) production increased with the increasing application dosages of biochar, while the PTMs uptakes in plant notably decreased after amendments. Conversion of kiwi pruning branches waste into emerging biochar benefits the agricultural waste recycling utilization and enhances PTMs-contaminated soil remediation in practice. Graphical abstract.