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用于去除水中新兴有机污染物的金属有机骨架。

Metal-Organic Frameworks for the Removal of Emerging Organic Contaminants in Water.

机构信息

Advanced Porous Materials Unit, IMDEA Energy Institute, Av. Ramón de la Sagra 3, 28935 Móstoles, Madrid, Spain.

出版信息

Chem Rev. 2020 Aug 26;120(16):8378-8415. doi: 10.1021/acs.chemrev.9b00797. Epub 2020 Feb 5.

Abstract

Water is essential in all aspects of life, being the defining characteristic of our planet and even our body. Regrettably, water pollution is increasingly becoming a challenge due to novel anthropogenic pollutants. Of particular concern are emerging organic contaminants (EOCs), the term used not only to cover newly developed compounds but also compounds newly discovered as contaminants in the environment. Aside from anthropogenic contamination, higher temperature and more extreme and less predictable weather conditions are projected to affect water availability and distribution. Therefore, wastewater treatment has to become a valuable water resource and its reuse is an important issue that must be carried out efficiently. Among the novel technologies considered in water remediation processes, metal-organic frameworks (MOFs) are regarded as promising materials for the elimination of EOCs since they present many properties that commend them in water treatment: large surface area, easy functionalizable cavities, some are stable in water, and synthesized at large scale, etc. This review highlights the advances in the use of MOFs in the elimination (adsorption and/or degradation) of EOCs from water, classifying them by the nature of the contaminant.

摘要

水在生活的各个方面都是必不可少的,它是我们星球甚至我们身体的决定性特征。遗憾的是,由于新型人为污染物,水污染日益成为一个挑战。特别令人关注的是新兴有机污染物(EOCs),这一术语不仅涵盖了新开发的化合物,还涵盖了在环境中作为污染物新发现的化合物。除了人为污染之外,预计更高的温度和更极端、更不可预测的天气条件将影响水的供应和分布。因此,废水处理必须成为有价值的水资源,其再利用是一个必须有效进行的重要问题。在被认为用于水修复过程的新型技术中,金属-有机骨架(MOFs)被认为是消除 EOCs 的有前途的材料,因为它们具有许多在水处理方面值得称赞的特性:大表面积、易于功能化的空腔、一些在水中稳定,并且可以大规模合成等。本综述重点介绍了 MOFs 在从水中消除(吸附和/或降解)EOCs 方面的应用进展,根据污染物的性质对它们进行了分类。

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