通过氮杂环烯烃（NHO）实现芳族碳-氟键的活化
Activation of Aromatic C-F Bonds by a N-Heterocyclic Olefin (NHO).
作者信息
Mandal Debdeep, Chandra Shubhadeep, Neuman Nicolás I, Mahata Alok, Sarkar Arighna, Kundu Abhinanda, Anga Srinivas, Rawat Hemant, Schulzke Carola, Mote Kaustubh R, Sarkar Biprajit, Chandrasekhar Vadapalli, Jana Anukul
机构信息
Tata Institute of Fundamental Research Hyderabad, Gopanpally, Hyderabad, 500107, India.
Institut für Chemie und Biochemie, Anorganische Chemie, Freie Universität Berlin, Fabeckstrasse 34-36, 14195, Berlin, Germany.
出版信息
Chemistry. 2020 May 12;26(27):5951-5955. doi: 10.1002/chem.202000276. Epub 2020 Apr 28.
A N-heterocyclic olefin (NHO), a terminal alkene selectively activates aromatic C-F bonds without the need of any additional catalyst. As a result, a straightforward methodology was developed for the formation of different fluoroaryl-substituted alkenes in which the central carbon-carbon double bond is in a twisted geometry.
一种氮杂环烯烃（NHO），一种末端烯烃，无需任何额外催化剂就能选择性地活化芳族C-F键。因此，开发了一种直接的方法来形成不同的氟芳基取代烯烃，其中中心碳-碳双键呈扭曲几何构型。
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