用于合成13族金属有机框架材料的六羟基三亚苯——一种具有β-方石英型结构的新型无机构筑单元
Hexahydroxytriphenylene for the synthesis of group 13 MOFs - a new inorganic building unit in a β-cristobalite type structure.
作者信息
Leubner S, Bengtsson V E G, Inge A K, Wahiduzzaman M, Steinke F, Jaworski A, Xu H, Halis S, Rönfeldt P, Reinsch H, Maurin G, Zou X, Stock N
机构信息
Institut für Anorganische Chemie, Christian-Albrechts-Universität, Max-Eyth-Straße 2, D 24118 Kiel, Germany.
Department of Materials and Environmental Chemistry, Stockholm University, SE-106 91 Stockholm, Sweden.
出版信息
Dalton Trans. 2020 Mar 9;49(10):3088-3092. doi: 10.1039/d0dt00235f.
Two new, microporous MOFs of framework composition ((CH3)2NH2)2[M3O(HHTP)(HHTP˙)], M = Al3+, Ga3+, H6HHTP = 2,3,6,7,10,11-hexahydroxytriphenylene, are described. Electron diffraction combined with molecular simulations show that these compounds crystallize in the β-cristobalite structure, containing a new type of trinuclear inorganic building unit for MOFs and radical anions.
本文描述了两种具有骨架组成((CH3)2NH2)2[M3O(HHTP)(HHTP˙)]的新型微孔金属有机框架材料（MOF），其中M = Al3+、Ga3+，H6HHTP = 2,3,6,7,10,11-六羟基三亚苯。电子衍射与分子模拟相结合表明，这些化合物以β-方石英结构结晶，包含一种新型的用于MOF的三核无机结构单元和自由基阴离子。
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