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通过熔融挤出制备的碳化硅填充聚丁二酸丁二醇酯复合材料的热机械性能

Thermomechanical Properties of SiC-Filled Polybutylene Succinate Composite Fabricated via Melt Extrusion.

作者信息

Lule Zelalem Chernet, Shiferaw Eyob Wondu, Kim Jooheon

机构信息

School of Chemical Engineering & Materials Science, Chung-Ang University, Seoul 156-756, Korea.

出版信息

Polymers (Basel). 2020 Feb 11;12(2):418. doi: 10.3390/polym12020418.

Abstract

Polybutylene succinate (PBS) composites filled with various mass fractions of silicon carbide (SiC) particles were fabricated via slow melt extrusion. The morphological analysis revealed that the fabrication technique assisted in achieving a good adhesion between the PBS and SiC, along with excellent filler dispersion throughout the PBS matrix. The inclusion of 40 wt.% SiC in the PBS composite afforded a 10 °C increase in the thermal degradation temperature and a 160% enhancement in the thermal conductivity relative to the neat PBS. The crystallization temperature also increased with the inclusion of SiC particles, thus making the composites easier to process. Furthermore, the improvement in the Young's modulus of the PBS composites increased their rigidity and stiffness relative to the neat PBS.

摘要

通过慢速熔融挤出制备了填充有不同质量分数碳化硅(SiC)颗粒的聚丁二酸丁二醇酯(PBS)复合材料。形态分析表明,该制备技术有助于实现PBS与SiC之间的良好粘附,以及在整个PBS基体中实现优异的填料分散。在PBS复合材料中加入40 wt.%的SiC,相对于纯PBS,热降解温度提高了10℃,热导率提高了160%。随着SiC颗粒的加入,结晶温度也升高,从而使复合材料更易于加工。此外,PBS复合材料杨氏模量的提高使其相对于纯PBS的刚性和硬度增加。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1704/7077630/11b004d32875/polymers-12-00418-g001.jpg

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