Cao Xu, Wang Weifan, Lu Kai, Yao Weiwei, Xue Fei, Ma Mengtao
College of Science, Nanjing Forestry University, Nanjing 210037, China.
College of Pharmacy, Nanjing University of Chinese Medicine, Nanjing 210023, China.
Dalton Trans. 2020 Mar 3;49(9):2776-2780. doi: 10.1039/d0dt00465k.
A low-valent magnesium(i) complex [(XylNacnac)Mg]2 was employed as a highly efficient precatalyst for the hydroboration of a variety of cyclic and linear organic carbonates, polycarbonates, CO2 and esters with HBpin under mild conditions. The resultant boronates can be used for the preparation of the corresponding value-added diols, triols or alcohols through hydrolysis.
一种低价态镁（I）配合物[(XylNacnac)Mg]₂被用作高效预催化剂，用于在温和条件下使各种环状和线性有机碳酸酯、聚碳酸酯、CO₂和酯与HBpin进行硼氢化反应。所得硼酸酯可通过水解用于制备相应的增值二醇、三醇或醇类。
