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通过盐熔法利用没食子酸交联高产率合成多孔碳氮衍生骨架。

Synthesis of a Porous CN-Derived Framework with High Yield by Gallic Acid Cross-Linking Using Salt Melts.

作者信息

Tian Zhihong, Heil Tobias, Schmidt Johannes, Cao Shaokui, Antonietti Markus

机构信息

School of Materials Science and Engineering, Zhengzhou University, Zhengzhou 450001, P. R. China.

Department of Colloid Chemistry, Max Planck Institute of Colloids and Interfaces, Potsdam 14476, Germany.

出版信息

ACS Appl Mater Interfaces. 2020 Mar 18;12(11):13127-13133. doi: 10.1021/acsami.9b20478. Epub 2020 Mar 5.

Abstract

Porous carbon/nitrogen frameworks are an emerging class of noble organic materials with a wide range of potential applications. However, the design and controlled synthesis of those materials are still a challenge. Herein, we present the rational design of such a system with high microporosity, specific surface areas of up to 946 m g, and excellent condensation yields. The obtained noble frameworks were used for the delivery of larger organic molecules and changed the melting behavior of some daily drug molecules along their highly polarizable surfaces.

摘要

多孔碳/氮骨架是一类新兴的具有广泛潜在应用的有机材料。然而,这些材料的设计和可控合成仍然是一个挑战。在此,我们展示了一种具有高微孔率、比表面积高达946 m²/g以及优异缩合产率的此类体系的合理设计。所获得的有机骨架用于递送较大的有机分子,并沿着其高度可极化的表面改变了一些日常药物分子的熔化行为。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f68c/7307830/36aba789b247/am9b20478_0002.jpg

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