• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

通过盐熔法利用没食子酸交联高产率合成多孔碳氮衍生骨架。

Synthesis of a Porous CN-Derived Framework with High Yield by Gallic Acid Cross-Linking Using Salt Melts.

作者信息

Tian Zhihong, Heil Tobias, Schmidt Johannes, Cao Shaokui, Antonietti Markus

机构信息

School of Materials Science and Engineering, Zhengzhou University, Zhengzhou 450001, P. R. China.

Department of Colloid Chemistry, Max Planck Institute of Colloids and Interfaces, Potsdam 14476, Germany.

出版信息

ACS Appl Mater Interfaces. 2020 Mar 18;12(11):13127-13133. doi: 10.1021/acsami.9b20478. Epub 2020 Mar 5.

DOI:10.1021/acsami.9b20478
PMID:32091193
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC7307830/
Abstract

Porous carbon/nitrogen frameworks are an emerging class of noble organic materials with a wide range of potential applications. However, the design and controlled synthesis of those materials are still a challenge. Herein, we present the rational design of such a system with high microporosity, specific surface areas of up to 946 m g, and excellent condensation yields. The obtained noble frameworks were used for the delivery of larger organic molecules and changed the melting behavior of some daily drug molecules along their highly polarizable surfaces.

摘要

多孔碳/氮骨架是一类新兴的具有广泛潜在应用的有机材料。然而，这些材料的设计和可控合成仍然是一个挑战。在此，我们展示了一种具有高微孔率、比表面积高达946 m²/g以及优异缩合产率的此类体系的合理设计。所获得的有机骨架用于递送较大的有机分子，并沿着其高度可极化的表面改变了一些日常药物分子的熔化行为。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f68c/7307830/98e3337818ef/am9b20478_0005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f68c/7307830/36aba789b247/am9b20478_0002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f68c/7307830/10cebbc82bd4/am9b20478_0006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f68c/7307830/e22ef39038e8/am9b20478_0004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f68c/7307830/f324467190bc/am9b20478_0001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f68c/7307830/98e3337818ef/am9b20478_0005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f68c/7307830/36aba789b247/am9b20478_0002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f68c/7307830/10cebbc82bd4/am9b20478_0006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f68c/7307830/e22ef39038e8/am9b20478_0004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f68c/7307830/f324467190bc/am9b20478_0001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f68c/7307830/98e3337818ef/am9b20478_0005.jpg

相似文献

1
Synthesis of a Porous CN-Derived Framework with High Yield by Gallic Acid Cross-Linking Using Salt Melts.通过盐熔法利用没食子酸交联高产率合成多孔碳氮衍生骨架。
ACS Appl Mater Interfaces. 2020 Mar 18;12(11):13127-13133. doi: 10.1021/acsami.9b20478. Epub 2020 Mar 5.
2
Template- and Metal-Free Synthesis of Nitrogen-Rich Nanoporous "Noble" Carbon Materials by Direct Pyrolysis of a Preorganized Hexaazatriphenylene Precursor.通过预组织的六氮杂三亚苯基前体直接热解无模板和无金属合成富氮纳米多孔“贵金属”碳材料。
Angew Chem Int Ed Engl. 2018 Aug 13;57(33):10765-10770. doi: 10.1002/anie.201804359. Epub 2018 Jul 26.
3
In Situ Expanding Pores of Dodecahedron-like Carbon Frameworks Derived from MOFs for Enhanced Capacitive Deionization.基于 MOFs 的十二面体碳框架原位扩孔用于增强电容去离子。
ACS Appl Mater Interfaces. 2017 May 3;9(17):15068-15078. doi: 10.1021/acsami.7b02712. Epub 2017 Apr 21.
4
Modular Design of Porous Soft Materials via Self-Organization of Metal-Organic Cages.通过金属有机笼的自组装实现多孔软材料的模块化设计
Acc Chem Res. 2018 Oct 16;51(10):2437-2446. doi: 10.1021/acs.accounts.8b00361. Epub 2018 Sep 25.
5
Carbon- and Nitrogen-Based Organic Frameworks.碳基和氮基有机骨架材料
Acc Chem Res. 2015 Jun 16;48(6):1591-600. doi: 10.1021/acs.accounts.5b00010. Epub 2015 May 22.
6
Stepwise Synthesis of Metal-Organic Frameworks.逐步合成金属有机骨架。
Acc Chem Res. 2017 Apr 18;50(4):857-865. doi: 10.1021/acs.accounts.6b00457. Epub 2017 Mar 28.
7
Metal-organic frameworks with functional pores for recognition of small molecules.具有功能孔的金属-有机骨架用于识别小分子。
Acc Chem Res. 2010 Aug 17;43(8):1115-24. doi: 10.1021/ar100023y.
8
Two-Dimensional Porous Polymers: From Sandwich-like Structure to Layered Skeleton.二维多孔聚合物：从类三明治结构到层状骨架
Acc Chem Res. 2018 Dec 18;51(12):3191-3202. doi: 10.1021/acs.accounts.8b00444. Epub 2018 Nov 9.
9
A Series of Layered Assemblies of Hydrogen-Bonded, Hexagonal Networks of C3-Symmetric π-Conjugated Molecules: A Potential Motif of Porous Organic Materials.一系列由 C3 对称 π 共轭分子氢键连接的六方网络层状组装体：多孔有机材料的潜在结构基元。
J Am Chem Soc. 2016 May 25;138(20):6617-28. doi: 10.1021/jacs.6b02968. Epub 2016 May 16.
10
Metal-Organic Frameworks as Platforms for Functional Materials.金属有机框架作为功能材料的平台
Acc Chem Res. 2016 Mar 15;49(3):483-93. doi: 10.1021/acs.accounts.5b00530. Epub 2016 Feb 15.

引用本文的文献

1
CN: A Class of Covalent Frameworks with Unique Properties.中文：一类具有独特性质的共价框架结构。
Adv Sci (Weinh). 2020 Nov 13;7(24):2001767. doi: 10.1002/advs.202001767. eCollection 2020 Dec.

本文引用的文献

1
Drug-encapsulated carbon (DECON): A novel platform for enhanced drug delivery.药物包裹碳（DECON）：一种用于增强药物传递的新型平台。
Sci Adv. 2019 Aug 14;5(8):eaax0780. doi: 10.1126/sciadv.aax0780. eCollection 2019 Aug.
2
Incorporation of functionalized carbon nanotubes into hydrophobic drug crystals for enhancing aqueous dissolution.将功能化碳纳米管掺入疏水性药物晶体中以提高水溶解度。
Colloids Surf B Biointerfaces. 2019 Jan 1;173:386-391. doi: 10.1016/j.colsurfb.2018.09.080. Epub 2018 Oct 1.
3
Dual-Porosity Hollow Carbon Spheres with Tunable Through-Holes for Multi-Guest Delivery.
具有可调贯穿孔的双重孔隙空心碳球用于多客体递药。
ACS Appl Mater Interfaces. 2018 Sep 19;10(37):31664-31673. doi: 10.1021/acsami.8b11825. Epub 2018 Sep 6.
4
Water-dispersible PEG-curcumin/amine-functionalized covalent organic framework nanocomposites as smart carriers for in vivo drug delivery.水散性 PEG-姜黄素/胺功能化共价有机骨架纳米复合材料作为体内药物输送的智能载体。
Nat Commun. 2018 Jul 17;9(1):2785. doi: 10.1038/s41467-018-04910-5.
5
Template- and Metal-Free Synthesis of Nitrogen-Rich Nanoporous "Noble" Carbon Materials by Direct Pyrolysis of a Preorganized Hexaazatriphenylene Precursor.通过预组织的六氮杂三亚苯基前体直接热解无模板和无金属合成富氮纳米多孔“贵金属”碳材料。
Angew Chem Int Ed Engl. 2018 Aug 13;57(33):10765-10770. doi: 10.1002/anie.201804359. Epub 2018 Jul 26.
6
Electrosprayed mesoporous particles for improved aqueous solubility of a poorly water soluble anticancer agent: in vitro and ex vivo evaluation.电喷雾介孔颗粒提高难溶性抗癌剂的水溶解度：体外和离体评价。
J Control Release. 2018 May 28;278:142-155. doi: 10.1016/j.jconrel.2018.03.031. Epub 2018 Mar 30.
7
The Concept of "Noble, Heteroatom-Doped Carbons," Their Directed Synthesis by Electronic Band Control of Carbonization, and Applications in Catalysis and Energy Materials.“高贵的、杂原子掺杂的碳”概念，通过碳化的电子能带控制定向合成，以及在催化和能源材料中的应用。
Adv Mater. 2018 May;30(21):e1706836. doi: 10.1002/adma.201706836. Epub 2018 Mar 26.
8
Tuning the Adsorption Energy of Methanol Molecules Along Ni-N-Doped Carbon Phase Boundaries by the Mott-Schottky Effect for Gas-Phase Methanol Dehydrogenation.通过 Mott-Schottky 效应调变 Ni-N 掺杂碳相界处甲醇分子的吸附能用于气相甲醇脱氢反应。
Angew Chem Int Ed Engl. 2018 Mar 1;57(10):2697-2701. doi: 10.1002/anie.201713429. Epub 2018 Feb 2.
9
Conductive Microporous Covalent Triazine-Based Framework for High-Performance Electrochemical Capacitive Energy Storage.用于高性能电化学电容储能的导电微孔共价三嗪基框架材料
Angew Chem Int Ed Engl. 2018 Jul 2;57(27):7992-7996. doi: 10.1002/anie.201711169. Epub 2017 Dec 4.
10
Activated carbon as a carrier for amorphous drug delivery: Effect of drug characteristics and carrier wettability.活性炭作为无定形药物递送的载体：药物特性和载体润湿性的影响。
Eur J Pharm Biopharm. 2017 Jun;115:197-205. doi: 10.1016/j.ejpb.2017.03.002. Epub 2017 Mar 8.